Hot metal de-sulphurisation is a dip-lance process involving the pneumatic injection of fine-grained de-sulphurisation reagents into the molten metal. For maximum efficiency the particles must be dispersed in the ladle as widely as possible to increase the total interfacial area which is primarily controlled by the lance design. Seven different lance configurations were modelled and simulated to determine the most efficient design using physical and mathematical modelling approach. A 0.25 scale plexi-glass model of the 100 T hot metal ladle was fabricated for the study. Residence time and mixing time studies were carried out using the electrical conductivity measurement technique through stimulus response of injected saturated salt solution. Mathematical modelling approach using momentum balance was used to simulate fluid flow profile of lance-ladle assembly under operating conditions using computational fluid dynamics package ANSYS-CFX. Based on the studies a new curved port lance has been designed which resulted in uniform and swirling flow profile inside the ladle without rotating the lance. Injection through the new lance increased the residence time of the particles and reduced the dead zones. The new design was fabricated and experimented at de-sulphurisation stations and has resulted in reduced flux consumption and treatment time.
Generation of high iron containing wastes such as mill scale, dust and sludge are inevitable in steel making process. It is important to develop and implement processes to recycle and re-use these wastes. An attractive option is to recycle these wastes through BOF steel making process, but is not suitable for handling and efficient operation in available forms. Present work shows the briquetting of steel making wastes using various binders in a pilot scale briquetting machine. In briquetting tests, the effecting parameters have been studied for determining the best combination of binders and operating parameters. A process for briquetting mill scale in optimum combination with CRM dust and BOF dusts using an organic binder has been established. Separate indices were formulated as acceptance criterion for use of mill scale briquettes in BOF service conditions involving dynamic, crushing, abrasive and thermal loads. Subsequently, series of trials were conducted with use of mill scale briquettes as secondary coolant replacing iron ore in 130T LD converter. The present paper compares the effect of mill scale briquettes vis-à-vis iron ore on process parameters in BOF steel making and also highlights its operational advantages.
Purpose
The purpose of the present study is to simulate the industrial hot-dip process of Zn-2.5Wt.%Mg-3 Wt.%Al and Zn-2.5 Wt.%Mg-9 Wt.%Al-0.15 Wt.%Si coatings and to study the effect of low and high Al variation on their microstructure, microhardness, adhesion and corrosion behaviour.
Design/methodology/approach
The hot-dip Zn-2.5 Mg-xAl coating simulation on steel substrate was carried out using a hot-dip process simulator. The microstructure of the coatings was characterized using a scanning electron microscope, energy dispersive spectroscopy and X-ray diffraction. The corrosion behaviour of the coatings was studied using a salt spray test in 5% NaCl solution as well as dynamic polarization in 3.5% NaCl solution.
Findings
Microhardness of the developed Zn-2.5 Mg-xAl coatings has been found to be approximately two times higher than that of the conventional galvanized coating. Zn-2.5 Mg-3Al coating has exhibited two times higher corrosion resistance as compared to that of Zn-2.5 Mg-9Al-0.15Si coating because of formation of more homogeneous and defect-free microstructure of the former. The MgZn2 phase has undergone preferential dissolution and provided Mg2+ ions to form a protective film.
Originality/value
The relative corrosion resistance of the two Zn–Al–Mg coatings with different Al content has been studied. The defect formed because of higher Al addition in the coating has been detected, and its effect on corrosion behaviour has been analysed.
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