We present the results of a new series of non-gray calculations of the atmospheres, spectra, colors, and evolution of extrasolar giant planets (EGPs) and brown dwarfs for effective temperatures below 1300 K. This theory encompasses most of the mass/age parameter space occupied by substellar objects and is the first spectral study down to 100 K. These calculations are in aid of the multitude of searches being conducted or planned around the world for giant planets and brown dwarfs and reveal the exotic nature of the class. Generically, absorption by H 2 at longer wavelengths and H 2 O opacity windows at shorter wavelengths conspire to redistribute flux blueward. Below 1200 K, methane is the dominant carbon bearing molecule and is a universal diagnostic feature of EGP and brown dwarf spectra. We find that the primary bands in which to search are Z (∼1.05 µm), J (∼1.2 µm), H (∼1.6 µm), K (∼2.2 µm), M (∼5 µm), and N (∼10 µm), that enhancements of the emergent flux over blackbody values, in particular in the near infrared, can be by many orders of magnitude, and that the infrared colors of EGPs and brown dwarfs are much bluer than previously believed. In particular, relative to J and H, the K band flux is reduced by CH 4 and H 2 absorption. Furthermore, we derive that for T eff s below 1200 K most or all true metals are sequestered below the photosphere, that an interior radiative zone is a generic feature of substellar objects, and that clouds of H 2 O and NH 3 are formed for T eff s below ∼400 K and ∼200 K, respectively. This study is done for solar-metallicity objects in isolation and does not include the effects of stellar insolation. Nevertheless, it is a comprehensive attempt to bridge the gap between the planetary and stellar realms and to develop a non-gray theory of objects from 0.3 M J ("saturn") to 70 M J (∼0.07 M ). We find that the detection ranges for brown dwarf/EGP -3discovery of both ground-and space-based telescopes are larger than previously estimated.

Using a model for refractory clouds, a novel algorithm for handling them, and the latest gas-phase molecular opacities, we have produced a new series of L and T dwarf spectral and atmosphere models as a function of gravity and metallicity, spanning the \teff range from 2200 K to 700 K. The correspondence with observed spectra and infrared colors for early- and mid-L dwarfs and for mid- to late-T dwarfs is good. We find that the width in infrared color-magnitude diagrams of both the T and L dwarf branches is naturally explained by reasonable variations in gravity and, therefore, that gravity is the "second parameter" of the L/T dwarf sequence. We investigate the dependence of theoretical dwarf spectra and color-magnitude diagrams upon various cloud properties, such as particle size and cloud spatial distribution. In the region of the L$\to$T transition, we find that no one cloud-particle-size and gravity combination can be made to fit all the observed data. Furthermore, we note that the new, lower solar oxygen abundances of Allende-Prieto, Lambert, & Asplund (2002) produce better fits to brown dwarf data than do the older values. Finally, we discuss various issues in cloud physics and modeling and speculate on how a better correspondence between theory and observation in the problematic L$\to$T transition region might be achieved.Comment: accepted to the Astrophysical Journal, 21 figures (20 in color); spectral models in electronic form available at http://zenith.as.arizona.edu/~burrow

We explore the spectral and atmospheric properties of brown dwarfs cooler than the latest known T dwarfs. Our focus is on the yet-to-be-discovered free-floating brown dwarfs in the T eff range from ∼800 K to ∼130 K and with masses from 25 to 1 M J . This study is in anticipation of the new characterization capabilities enabled by the launch of SIRTF and the eventual launch of JWST. In addition, it is in support of the continuing ground-based searches for the coolest substellar objects. We provide spectra from ∼0.4 µm to 30 µm , highlight the evolution and mass dependence of the dominant H 2 O, CH 4 , and NH 3 molecular bands, consider the formation and effects of water-ice clouds, and compare our theoretical flux densities with the putative sensitivities of the instruments on board SIRTF and JWST. The latter can be used to determine the detection ranges from space of cool brown dwarfs. In the process, we determine the reversal point of the blueward trend in the near-infrared colors with decreasing T eff (a prominent feature of the hotter T dwarf family), the T eff s at which water and ammonia clouds appear, the strengths of gas-phase ammonia and methane bands, the masses and ages of the objects for which the neutral alkali metal lines (signatures of L and T dwarfs) are muted, and the increasing role as T eff decreases of the mid-infrared fluxes longward of 4 µm . These changes suggest physical reasons to expect the emergence of at least one new stellar class beyond the T dwarfs. Furthermore, studies in the mid-infrared could assume a new, perhaps transformational, importance in the understanding of the coolest brown dwarfs. Our spectral models populate, with cooler brown dwarfs having progressively more planet-like features, the theoretical gap between the known T dwarfs and the known giant planets. Such objects likely inhabit the galaxy, but their numbers are as yet unknown.

We show that under certain circumstances the differences between the absorption mean and Planck mean opacities can lead to multiple solutions for an LTE atmospheric structure. Since the absorption and Planck mean opacities are not expected to differ significantly in the usual case of radiative equilibrium, non-irradiated atmospheres, the most interesting situations where the effect may play a role are strongly irradiated stars and planets, and also possibly structures where there is a significant deposition of mechanical energy, such as stellar chromospheres and accretion disks. We have presented an illustrative example of a strongly irradiated giant planet where the bifurcation effect is predicted to occur for a certain range of distances from the star.

We generate theoretical albedo and reflection spectra for a full range of extrasolar giant planet (EGP) models, from Jovian to 51-Pegasi class objects. Our albedo modeling utilizes the latest atomic and molecular cross sections, a Mie theory treatment of extinction by condensates, a variety of particle size distributions, and an extension of the Feautrier radiative transfer method which allows for a general treatment of the scattering phase function. We find that due to qualitative similarities in the compositions and spectra of objects within each of five broad effective temperature ranges, it is natural to establish five representative EGP albedo classes: a ``Jovian'' class (T$_{\rm eff} \lesssim 150$ K; Class I) with tropospheric ammonia clouds, a ``water cloud'' class (T$_{\rm eff} \sim 250$ K; Class II) primarily affected by condensed H$_2$O, a ``clear'' class (T$_{\rm eff} \gtrsim 350$ K; Class III) which lacks clouds, and two high-temperature classes: Class IV (900 K $\lesssim$ T$_{\rm{eff}}$ $\lesssim$ 1500 K) for which alkali metal absorption predominates, and Class V (T$_{\rm{eff}}$ $\gtrsim$ 1500 K and/or low surface gravity ($\lesssim$ 10$^3$ cm s$^{-2}$)) for which a high silicate layer shields a significant fraction of the incident radiation from alkali metal and molecular absorption. The resonance lines of sodium and potassium are expected to be salient features in the reflection spectra of Class III, IV, and V objects. We derive Bond albedos and effective temperatures for the full set of known EGPs and explore the possible effects of non-equilibrium condensed products of photolysis above or within principal cloud decks. As in Jupiter, such species can lower the UV/blue albedo substantially, even if present in relatively small mixing ratios.Comment: revised LaTeX manuscript accepted to Ap.J.; also available at http://jupiter.as.arizona.edu/~burrows/paper