The analysis of water quality, regarding the content of metals, especially heavy and radioactive ones, has been carried out in an indirect way, by testing scale formed in a hot-water heater, using water from the water-supply network of the city of Belgrade – the district of New Belgrade. The determination of the composition and the structure of the scale has resulted in its complete identification, and its crystallochemical formula has been defined. It has unequivocally been established that the obtained results are within the tolerance boundary with the results acquired by a conventional analysis of water, when it is a matter of very low concentrations. The presence of radioactive elements of uranium and strontium in a scale sample has been found and the way of their penetrating its composition and structure has been explained. Applying the fractional extraction method, uranium has been established to be of an anthropogenic origin.
Many high purity salts are produced by dissolving pure metal in non-oxidizing mineral acids. If hydrogen overpotential on the given metal is high, then the rate of overall process is defined by reaction of hydrogen ion reduction. This study investigated the possibility of accelerated dissolving of metal zinc in sulphuric acid by introducing copper cathode on which evolving hydrogen is much easier than on zinc. It was found out that the acceleration of zinc dissolving is possible and, at constant surface of copper cathode depends on the quality of electrical contact between copper electrode and zinc
This paper shows the results of investigations of corrosion resistance of different samples of chromium-nickel steels Č 4574 and Č 4583 in calcium-hypochlorite solution, by potentiodynamic method. The paper presents continuation of investigations on steels URANUS B6 and Č 4578 published in reference [1]. In this paper comparison of the obtained results is carried out, too, in order to detect steel, which quality is the best choice for calcium hypo chlorite solution requirements
This paper presents the experimental results of the extraction of lead and silver from a lead-silver waste cake obtained in the process of hydrometallurgical zinc production. While controlling the pH value, the lead-silver cake was leached at a temperature close to boiling point in different concentrations of aqueous calcium chloride solutions. The experiments were performed applying different ratios between the mass of cake and the volume of the leaching agent under different durations of the process. It was concluded that at the optimal process parameters (pH 2.0-2.5; CaCl 2 concentration, 3.6 mol dm -3 ; temperature, 95 °C; solid/liquid ratio, 1:5), the leaching efficiency of lead and silver could reach the approximate value of 94 %. Applying the same optimal process parameters, the method was applied to the leaching of a lead-silver cake in a magnesium chloride solution, but with significantly lower efficiencies. The results show that leaching of lead and silver in a calcium chloride solution could be a prospective method for increasing the recovery of lead and silver during hydrometallurgical zinc production.
Corrosion resistance of Cr - Ni (special steels) specimen is tested by electrochemical methods, numerical method of linear polarization and polarization resistance method in calcium-hypochlorite (Ca(OCl)2) solutions. With increasing of Ca(OCl)2 concentration, pH value of the solution increases, as well as active chlorine concentration and corrosion activity of the medium. According to the quantitative method of the corrosion resistance determination it can be concluded that the steels tested in 1 wt % Ca(OCl)2 solution are resistant, in 10 wt % solution constant, and in 50 wt % suspension less resistant. URANUS B6 showed the best corrosion resistance of all tested chromium - nickel steels in all tested corrosion mediums
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