An experimental investigation of the explosions of 2 in. diameter glass spheres under high internal pressure has been made. The spheres were initially filled with air or helium at 400 and 326 p.s.i., respectively, and were exploded in air at atmospheric pressure. Experiments on the simulation of high-altitude explosions are also described. Schlieren and spark shadowgraph records of explosion phenomena, and pressure records of the reflexion of the spherical shock wave at various radii, are presented.An account of some initial experiments on the implosion of 5 in. diameter glass spheres is given. The results were not very satisfactory because of the failure of the spheres to shatter in a desirable manner while under an external pressure of 65 p.s.i.Numerical solutions to the air and helium sphere explosions are described and the experimental wave phenomena are shown to be in good quantitative agreement with the theoretical predictions, in that they exhibit all the main features that were predicted and are modified only by the physical limitations of the glass diaphragm. A formation process is associated with the spherical shock waves in practice, resulting in initial shock velocities which are lower than the theoretical values.

Remarks on nonequilibrium contributions to the rate of chemical reaction in the Lorentz gas J. Chem. Phys. 95, 6192 (1991); 10.1063/1.461594Stochastic thermodynamics of nonequilibrium steady states in chemical reaction systems

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