— Weathering effects on meteorite finds from the Acfer region were studied by various analytical techniques and in dependence on the depth of sampling. In thin sections of weathered meteorites, weathering effects usually decrease from the outside to the interior of the meteorite. The results of evolved gas analysis indicate that variation in weathering between surface and core is not significant in respect to the formation of Fe‐oxyhydroxides. The secondary alteration effects in the noble gases are distributed unevenly throughout the specimens, as seen in the nonsystematic differences observed for the heavy noble gases. Chemical analyses show significant enrichment of Ba and Sr in the outer parts of the weathered samples due to element contamination through aqueous solution. Iron, Ni, and Co are partly flushed from the system as the metal oxidation proceeds. Oxygen isotopes show increases in δ18O and δ17O with increasing terrestrial age. For a set of H3 chondrites, the degree of weathering determined from the water content was correlated with terrestrial ages and is discussed with respect to possible weathering mechanisms.
The average δ 13 C-value of glycerol from plant origin is 4-5‰ more negative than that of carbohydrates from the same source. This depletion is exclusively dealing with position C-1 of the molecule. This is also observed for glycerol from other natural sources, although to a smaller extent, while synthetic glycerol shows a statistical 13 C-pattern. On the basis of these data an illegal addition of glycerol to wine should be detectable. In fermentations of glucose with yeast the extent of the depletion in position C-1 of glycerol proved to be reciprocal to its yield. Furthermore a total carbon and isotope balance showed that the depletion of glycerol is a compensation for small 13 C-enrichments in the corresponding positions of main products. An isotope effect on the aldolase reaction and a noncomplete equilibration of the triose phosphates are discussed as main reasons for these findings.
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