Stretchable organic light-emitting diodes are ubiquitous in the rapidly developing wearable display technology. However, low efficiency and poor mechanical stability inhibit their commercial applications owing to the restrictions generated by strain. Here, we demonstrate the exceptional performance of a transparent (molybdenum-trioxide/gold/molybdenum-trioxide) electrode for buckled, twistable, and geometrically stretchable organic light-emitting diodes under 2-dimensional random area strain with invariant color coordinates. The devices are fabricated on a thin optical-adhesive/elastomer with a small mechanical bending strain and water-proofed by optical-adhesive encapsulation in a sandwiched structure. The heat dissipation mechanism of the thin optical-adhesive substrate, thin elastomer-based devices or silicon dioxide nanoparticles reduces triplet-triplet annihilation, providing consistent performance at high exciton density, compared with thick elastomer and a glass substrate. The performance is enhanced by the nanoparticles in the optical-adhesive for light out-coupling and improved heat dissipation. A high current efficiency of ~82.4 cd/A and an external quantum efficiency of ~22.3% are achieved with minimum efficiency roll-off.

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We report the confinement of recombination zone (RZ) in green phosphorescent organic light-emitting diodes (Ph-OLEDs) for enhanced efficiency by varying the emission layer (EML) thickness and through quantum well (QW) insertion. At low thickness of EML, the efficiency is reduced owing to the diffusion of the RZ toward the EML/hole transport layer interface, which was revealed through the presence of exciton blocking layer [TCTA: tris­(4-carbazoyl-9-ylphenyl)­amine] excitation accompanied by a blue-shift in electroluminescence (EL). Further increase in the thickness of the EML caused the RZ to move toward the cathode, which was determined based on the disappearance of TCTA emission and the corresponding red-shift observed in EL spectra. The solid-state and time-resolved area normalized photoluminescence emission spectra investigations further corroborate the RZ movement tactics along with TCTA excimer generation and exciplex generation between TCTA and tris­[2-phenylpyridinato-C2,N]­iridium­(III) Ir­(ppy)3. The superior quantum and current efficiency of 14.4% and 50 cd/A, respectively, were determined for the device with an EML thickness of 15 nm due to the confinement of the RZ in the EML. The addition of (EML/interlayer/EML) QW facilitates improved charge balance in the Ph-OLED and further assists in the confinement of the RZ in the EML. Because of QW, a slight increment in quantum (14.6%) and current efficiency (52 cd/A) was observed. Without using any sensing layers, movement of the RZ was successfully monitored and confined in the EML to realize enhanced efficiency in green Ph-OLEDs.