A schematic of selective electrochemical CO2 conversion to multicarbon alcohols on N-doped porous carbon-supported Cu catalysts via a two-site mechanism is shown.

The phospholipase A 2 (PLA 2 ) superfamily of lipolytic enzymes is involved in a number of essential biological processes, such as inflammation, development, host defense, and signal transduction. Despite the proven involvement of plant PLA 2 s in many biological functions, including senescence, wounding, elicitor and stress responses, and pathogen defense, relatively little is known about plant PLA 2 s, and their genes essentially remain uncharacterized. We characterized three of four Arabidopsis thaliana PLA 2 paralogs (PLA 2 -b, -g, and -d) and found that they (1) are expressed during pollen development, (2) localize to the endoplasmic reticulum and/or Golgi, and (3) play critical roles in pollen development and germination and tube growth. The suppression of PLA 2 using the RNA interference approach resulted in pollen lethality. The inhibition of pollen germination by pharmacological PLA 2 inhibitors was rescued by a lipid signal molecule, lysophosphatidyl ethanolamine. Based on these results, we propose that plant reproduction, in particular, male gametophyte development, requires the activities of the lipid-modifying PLA 2 s that are conserved in other organisms.

ARM TrustZone, which provides a Trusted Execution Environment (TEE), normally plays a role in keeping security-sensitive resources safe. However, to properly control access to the resources, it is not enough to just isolate them from the Rich Execution Environment (REE). In addition to the isolation, secure communication should be guaranteed between security-critical resources in the TEE and legitimate REE processes that are permitted to use them. Even though there is a TEE security solution -namely, a kernel-integrity monitorit aims to protect the REE kernel's static regions, not to secure communication between the REE and TEE.We propose SeCReT to ameliorate this problem. SeCReT is a framework that builds a secure channel between the REE and TEE by enabling REE processes to use session keys in the REE that is regarded as unsafe region. SeCReT provides the session key to a requestor process only when the requestor's code and control flow integrity are verified. To prevent the key from being exposed to an attacker who already compromised the REE kernel, SeCReT flushes the key from the memory every time the processor switches into kernel mode.

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The purpose of this study was to measure and correlate the fitness and trueness of a 3-unit fixed dental prosthesis (FDP) fabricated using two digital workflows. The 3-unit FDPs were fabricated using two digital workflows (N = 15). The digital workflows were divided into chairside (closed type) and in-lab (open type) groups. The scanning, computer-aided design (CAD), and computer-aided manufacturing (CAM) processes were conducted with 3shape E1 scanner, exocad CAD software, and DDS EZIS HM, respectively, in the in-lab group; and with CEREC omnicam intraoral scanner, CEREC CAD software, and CEREC MC XL, respectively, in the chairside group. The fitness of the fabricated 3-unit FDPs was evaluated by scanning the silicone replica of the cement space and analyzing the thickness of the silicone replica in the three-dimensional (3D) inspection software (Geomagic control X). The trueness of the milling unit was analyzed by 3D analysis of the CAD reference model, which is the design file of the 3-unit FDP, and the CAD test model, which is the scanned file of the 3-unit FDP. In the statistical analysis, comparison of the two groups was conducted by Mann–Whitney U test, and the correlation between the fitness and trueness was conducted by Pearson correlation test (α = 0.05). The marginal and internal fit were significantly lower in the in-lab group at all measurement positions (p < 0.001). The trueness of the milling unit was significantly higher in the in-lab group compared to the chairside group (p < 0.001). There was a positive correlation between the trueness and internal fit (correlation coefficient = 0.621) in the in-lab group (p = 0.013). The use of appropriate equipment in an in-lab (open type) digital workflow enables a better fabrication of 3-unit FDPs than a chairside (closed type) digital workflow, and poor trueness on the inner surface of the crown adversely affects the internal fit.