The thermoelectric properties of mixed oxides I n, O, ~MO, (MO, = Cr203, Mn203, NiO, ZnO, Y203, Nb205, SnOJ are investigated in terms of the thermoelectric materials at high temperature. The Seebeck coefficients, S, of all the samples have negative values, and those of I n, O, . SnO, and In,O,.ZnO increase linearly with temperature, attaining values of -90 and -210 pV K-' at 1000 "C, respectively. The electrical conductivities, B , of these oxides are significantly high. The power factor S2a of the oxides has constantly positive temperature coefficients up to over 1000 "C. Rather low thermal conductivities, IC, of the sintered bodies of the oxides, ca. 1.7 W m-' K-' at room temperature, lead to the largest value of the thermoelectric figure of merit Z=0.4 x l o v 4 K-' for M =Sn at 1000 "C, and the Z value increases toward higher temperatures.

In this study, supercooling effects on the hygrothermal behavior of fired clay materials under various experimental conditions, such as water content, cooling rates, and size of specimens were investigated using experimental methods and hygrothermal simulations. We report results of the differential scanning calorimetry (DSC) and temperature distribution changes during a freeze–thaw (FT) experiment using unsaturated specimens. Also, we developed a numerical model of the freezing and thawing processes including the supercooling processes. The DSC results show the freezing of the supercooled water in a fired clay material is considerably faster than that in cement-based materials. It was also found that the dependency of the supercooling effects on the cooling rates seemed to be small. When the water saturation of a material decreases, the rate of the ice saturation increase during the freezing of the supercooled water is decreased while the freezing points of the supercooled water was not changed considerably. The comparison of the results of the FT experiment and hygrothermal simulations show that the combination of the existed hygrothermal model and a modified kinetic equation can reproduce the rapid temperature rise during the freezing of the supercooling water in the FT experiment. Finally, the size effects of specimens on the supercooling phenomenon was discussed based on the experimental and calculation results. The freezing points got higher when a specimen was larger. Due to differences in the ratio of the surface area to the volume, hygrothermal behavior in small specimens and relatively large specimens like that of the DSC and the FT experiment, respectively were markedly different. Water in a relatively large specimen with a small ratio of surface area to volume can achieve the thermodynamic equilibrium in a short period after the freezing starts.

To investigate the supercooling phenomenon in fired clay materials, low-temperature differential scanning calorimetry (DSC) and a one-dimensional freeze-thaw (FT) experiment were performed on saturated specimens. The rate of increase in ice saturation during freezing was calculated from the DSC result. Rapid ice growth over a relatively narrow temperature range (within about 0.2 K) was observed at a cooling rate of 0.25 K/min. In the FT experiment, the temperature distribution of a specimen was measured with inserted thermocouples. According to the results of the FT experiment, a rapid temperature increase was observed at sub-zero temperatures accompanied by freezing of the supercooled water. When the supercooled water began to freeze, the released latent heat was found to strongly prevent the specimen temperature from dropping even during the cooling period. Finally, a hygrothermal model of freezing and thawing including a non-equilibrium supercooling process was developed. The freezing rate of the supercooled water was modelled based on the DSC result. The validity of the model was verified by comparing the results of the FT experiment and calculations. The model was found to be able to replicate the rapid temperature rise during the cooling period of the FT experiment.

Frost action is one of the main causes for deterioration of porous building materials under defined hygrothermal conditions. For an accurate assessment of the frost damage risk under various environmental conditions, thermal, moisture, and mechanical properties should be considered; the hygrothermal properties affect the distribution of temperature and amount of frozen water in the material, whereas the mechanical properties are necessary to predict deformation and damage. Moreover, the dependency of these properties on the moisture content should be understood. Therefore, in this study, thermal, moisture, and mechanical properties of wet and dry fired clay materials were measured. The fired clay materials were sintered at two different temperatures, 1000 °C and 1100 °C (samples T10 and T11, respectively) for comparison. The measured thermal and mechanical properties are considerably different in the wet state compared to the dry state. Freeze–thaw tests were conducted to investigate the relation between the material properties and the frost resistance under a simple experimental condition. As expected, based on the pore structure and obtained mechanical properties, T10 exhibited lower frost resistance than T11 in the freeze–thaw test. Finally, frost damage risk was assessed under various environmental conditions based on the obtained hygrothermal and mechanical properties.

Cultural properties are variously influenced by their surrounding environmental conditions. One of the reasons for the deterioration of mural paintings in the Takamatsuzuka Tumulus was the humid microclimate on their surface. In order to control the deterioration of mural paintings caused by such problems, it is important to investigate the environmental factors from various aspects, such as the temperature, humidity, water content of cultural properties, wetting and drying cycles and so on. As for the research concerning hygrothermal behavior on mural paintings, these variables may not be thoroughly predicted by 1-D or 2-D for determination of the location and degree of the deterioration of mural paintings. This paper shows how a 3-D hygrothermal model developed with a view to analyzing the preservation measures that allow quantifying of the degree of drying and condensing processes occurred on the surfaces of the underground chamber. The findings show that for the purpose of preserving mural paintings within the underground chamber, the temperature difference between the surrounding mound and the protected object should be kept as constant as can be practically achieved. This method is applicable for estimating the effects of preservation measures for the conservation of other mural paintings.