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The Bayesian neural network (BNN) method is proposed to predict the isotopic cross-sections in proton induced spallation reactions. Learning from more than 4000 data sets of isotopic cross-sections from 19 experimental measurements and 5 theoretical predictions with the SPACS parametrization, in which the mass of the spallation system ranges from 36 to 238, and the incident energy from 200 MeV/u to 1500 MeV/u, it is demonstrated that the BNN method can provide good predictions of the residue fragment cross-sections in spallation reactions.

Mechanochromic luminescence materials have attracted rapidly growing interest. Nevertheless, the designed synthesis of such materials remains a challenge, and there have been few examples based on weak intramolecular interactions. Herein, we report a new approach for preparing mechanochromic luminescence materials of Cu­(I) complexes, i.e., constructing a photoluminescence system that bears a large coplanar multinuclear Cu­(I) unit showing weak intramolecular π···π interactions with the planar rings of the coordinated ligands in the molecule. Using it, a series of novel mechanochromic luminescent tetranuclear Cu­(I) complexes have been successfully designed and synthesized. As revealed by single-crystal X-ray crystallography, these Cu­(I) complexes share an identical {Cu4[μ3-η2(N,N),η1(N),η1(N)-pyridyltetrazole]2}2+ planar fragment whose coplanar pyridyl rings exhibit weak intramolecular π···π interactions with the phenyl rings of the coordinated phosphine ligands in the molecule. All of these Cu­(I) complexes exhibit reversible mechanochromic luminescence, which can be attributed to the change in the rigidity of the molecular structure resulting from the disruption and restoration of intramolecular π···π interactions between the pyridyl and phenyl rings triggered by grinding and CH2Cl2 vapor, as supported by powder X-ray diffraction and Fourier transform infrared spectrometry. In addition, the results might provide a new route for developing mechanochromic luminescence materials of Cu­(I) complexes for intelligent responsive luminescent devices.