To build a flexible and interpretable model for document analysis, we develop deep autoencoding topic model (DATM) that uses a hierarchy of gamma distributions to construct its multi-stochastic-layer generative network. In order to provide scalable posterior inference for the parameters of the generative network, we develop topic-layer-adaptive stochastic gradient Riemannian MCMC that jointly learns simplexconstrained global parameters across all layers and topics, with topic and layer specific learning rates. Given a posterior sample of the global parameters, in order to efficiently infer the local latent representations of a document under DATM across all stochastic layers, we propose a Weibull upward-downward variational encoder that deterministically propagates information upward via a deep neural network, followed by a Weibull distribution based stochastic downward generative model. To jointly model documents and their associated labels, we further propose supervised DATM that enhances the discriminative power of its latent representations. The efficacy and scalability of our models are demonstrated on both unsupervised and supervised learning tasks on big corpora.
The thermooxidative aging of ammoniacatalyzed phenolic resin for 30 days at 60-170 C was investigated in this article. The aging mechanism and thermal properties of the phenolic resin during thermooxidative aging were described by thermogravimetry (TG)-Fourier transform infrared (FTIR) spectroscopy, attenuated total reflectance (ATR)-FTIR spectroscopy, and dynamic mechanical thermal analysis. The results show that the CAN bond decomposed into ammonia and the dehydration condensation between the residual hydroxyl groups occurred during the thermooxidative aging. Because of the presence of oxygen, the methylene bridges were oxidized into carbonyl groups. After aging for 30 days, the mass loss ratio reached 4.50%. The results of weight change at high temperatures coincided with the results of TG-FTIR spectroscopy and ATR-FTIR spectroscopy. The glass-transition temperature (T g ) increased from 240 to 312 C after thermooxidative aging for 30 days, which revealed the postcuring of phenolic resins. In addition, an empirical equation between the weight change ratio and T g was obtained.
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