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The United States faces a significant burden in treating 0.61billionkg of defective tomatoes (culls) every year. We present a proof-of-concept for generating electricity from culled tomatoes in microbial-electrochemical systems (MESs). This study delineates impedance behavior of the culled tomatoes in MESs and compares its impedance spectra with that of soluble substrates (dextrose, acetate, and wastewater). A series of AC and DC diagnostic tests have revealed the superior performance of the culled tomatoes compared to the pure substrates. Cyclic voltammetry results have indicated the active role of indigenous, diffusible redox-active pigments in the culled tomatoes on overall electricity production. Electrochemical impedance spectroscopy results have elucidated the role of peel and seed on the oxidation behavior of the culled tomatoes.

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Mixed carbonate and siliciclastic marine sediments commonly become freshwater aquifers in eastern coastal regions of the United States and many other global locations. As these deposits age, the carbonate fraction of the sediment is commonly removed by dissolution and the aquifer can become a solely siliciclastic system or contain zones or beds of pure quartz sand. During aquifer evolution, the sediment grain size characteristics, hydraulic conductivity, and porosity change. An investigation of these changes using mixed carbonate/siliciclastic sediment samples collected from a modern barrier island beach in southern Florida showed that the average mean grain diameter decreased with removal of the carbonate fraction, but the average hydraulic conductivity and porosity increased slightly, but not to statistical significance. This counterintuitive result occurs because of the change in the pore types from a combined shelter and intergranular pore system producing a dual porosity system in the mixed sediments to a single intergranular pore system in the siliciclastic sediment fraction. Within the mixed carbonate/siliciclastic sediment, in the pure carbonate fraction, large shell fractions form grain-supported large pores, which become filled with sand-sized quartz as the shell fragments decrease in size or as the sediment becomes compacted. The hydraulic conductivity increases because the shell fragments that were oriented perpendicular to flow caused an increase in the length of the flow path, or a larger scale tortuosity, compared with the flow through pure quartz sand.