Previously, we 3D-printed polymer-zeolite monoliths by layer-wise phase separation. Importantly, this technique used liquid printing dopes, which exhibit a better rheology than traditional bentonite inks. In this work, we expanded polymer printing to metal−organic frameworks (MOFs) to address their rheological limitations. Initially, MOF-74 and HKUST-1 monoliths, with a composition of 40 wt % MOF and 60 wt % polyamide(imide) (Torlon), were printed. However, only HKUST-1 exhibited full crystalline retention. In contrast, the polymer solvents partially decomposed MOF-74, and the retained crystals were used as growth seeds. This approach produced dense MOF film monoliths with 40 wt % loading. The analysis of CO 2 adsorption capacities revealed CO 2 uptakes proportional to MOF loading for HKUST-1@Torlon monoliths. Moreover, secondary growth led to a 5-fold increase in CO 2 capacity for MOF-