Poly(lactic acid) (PLA) is one of the most often used polymers in 3D printing based on the fused deposition modeling (FDM) method. On the other hand, PLA is also a shape memory polymer (SMP) with a relatively low glass transition temperature of ~60 °C, depending on the exact material composition. This enables, on the one hand, so-called 4D printing, i.e., printing flat objects which are deformed afterwards by heating them above the glass transition temperature, shaping them and cooling them down in the desired shape. On the other hand, objects from PLA which have been erroneously deformed, e.g., bumpers during an accident, can recover their original shape to a certain amount, depending on the applied temperature, the number of deformation cycles, and especially on the number of broken connections inside the object. Here, we report on an extension of a previous study, investigating optimized infill designs which avoid breaking in 3-point bending tests and thus allow for multiple repeated destruction and recovery cycles with only a small loss in maximum force at a certain deflection.

Shape-memory polymers (SMPs) can be deformed, cooled down, keeping their new shape for a long time, and recovered into their original shape after being heated above the glass or melting temperature again. Some SMPs, such as poly(lactic acid) (PLA), can be 3D printed, enabling a combination of 3D-printed shapes and 2D-printed, 3D-deformed ones. While deformation at high temperatures can be used, e.g., to fit orthoses to patients, SMPs used in protective equipment, bumpers, etc., are deformed at low temperatures, possibly causing irreversible breaks. Here, we compare different typical infill patterns, offered by common slicing software, with self-designed infill structures. Three-point bending tests were performed until maximum deflection as well as until the maximum force was reached, and then the samples were recovered in a warm water bath and tested again. The results show a severe influence of the infill pattern as well as the printing orientation on the amount of broken bonds and thus the mechanical properties after up to ten test/recovery cycles.