Nanocomposite strain sensors, particularly those consisting of polymer–graphene composites, are increasingly common and are of great interest in the area of wearable sensors. In such sensors, application of strain yields an increase in resistance due to the effect of deformation on interparticle junctions. Typically, widening of interparticle separation is thought to increase the junction resistance by reducing the probability of tunnelling between conducting particles. However, an alternative approach would be to use piezoresistive fillers, where an applied strain modifies the intrinsic filler resistance and so the overall composite resistance. Such an approach would broaden sensing capabilities, as using negative piezoresistive fillers could yield strain-induced resistance reductions rather than the usual resistance increases. Here, we introduce nanocomposites based on polyethylene oxide (PEO) filled with MoS2 nanosheets. Doping of the MoS2 by the PEO yields nanocomposites which are conductive enough to act as sensors, while efficient stress transfer leads to nanosheet deformation in response to an external strain. The intrinsic negative piezoresistance of the MoS2 leads to a reduction of the composite resistance on the application of small tensile strains. However, at higher strain the resistance grows due to increases in junction resistance. MoS2–PEO composite gauge factors are approximately −25 but fall to −12 for WS2–PEO composites and roughly −2 for PEO filled with MoSe2 or WSe2. We develop a simple model, which describes all these observations. Finally, we show that these composites can be used as dynamic strain sensors.

While polymers are typically processed using methods such as compression molding, injection molding, extrusion, and thermoforming, [10] polymer nanocomposites are typically prepared by solution blending, melt mixing/compounding, in situ polymerization, and composite self-assembly. [11] Nanocomposite formation by printing is somewhat less common. [12] Depending on the matrix, nanocomposite materials can be very soft and so skin mountable. [1] They also have high working strain ranges making them ideal candidates for emerging areas such as wearable sensing. [13,14] Although their elec-Research data are not shared.

Piezoresistivity of resin-impregnated carbon nanotube film at high temperatures Min Li, Tianyi Zuo, Shaokai Wang et al.