propene at 30 1C. This makes them promising separation materials for both liquid membranes and absorber fluids due to their high silver content and significant propene capacity. Single (iGSC) and mixed (NMR) gas solubilities as well as diffusion coefficients (PFG-NMR) of propene and propane were determined to predict the theoretical selectivity of solubility, membrane selectivity, capacity and transport properties of the silver salts according to the solution diffusion model. A strong influence of the number and type of ligands on chemical complexation, physicochemical properties and separation performance has been observed.