We have complemented existing observations of H i absorption with new observations of HCO+, C2H, HCN, and HNC absorption from the Atacama Large Millimeter/submillimeter Array and the Northern Extended Millimeter Array in the directions of 20 background radio continuum sources with 4° ≤ ∣b∣ ≤ 81° to constrain the atomic gas conditions that are suitable for the formation of diffuse molecular gas. We find that these molecular species form along sightlines where A V ≳ 0.25, consistent with the threshold for the H i-to-H2 transition at solar metallicity. Moreover, we find that molecular gas is associated only with structures that have an H i optical depth >0.1, a spin temperature <80 K, and a turbulent Mach number ≳ 2. We also identify a broad, faint component to the HCO+ absorption in a majority of sightlines. Compared to the velocities where strong, narrow HCO+ absorption is observed, the H i at these velocities has a lower cold neutral medium fraction and negligible CO emission. The relative column densities and linewidths of the different molecular species observed here are similar to those observed in previous experiments over a range of Galactic latitudes, suggesting that gas in the solar neighborhood and gas in the Galactic plane are chemically similar. For a select sample of previously observed sightlines, we show that the absorption line profiles of HCO+, HCN, HNC, and C2H are stable over periods of ∼3 yr and ∼25 yr, likely indicating that molecular gas structures in these directions are at least ≳100 au in size.

We compare observations of H i from the Very Large Array (VLA) and the Arecibo Observatory and observations of HCO+ from the Atacama Large Millimeter/submillimeter Array (ALMA) and the Northern Extended Millimeter Array (NOEMA) in the diffuse (A V ≲ 1) interstellar medium (ISM) to predictions from a photodissociation region (PDR) chemical model and multiphase ISM simulations. Using a coarse grid of PDR models, we estimate the density, FUV radiation field, and cosmic-ray ionization rate (CRIR) for each structure identified in HCO+ and H i absorption. These structures fall into two categories. Structures with T s < 40 K, mostly with N(HCO+) ≲ 1012 cm−2, are consistent with modest density, FUV radiation field, and CRIR models, typical of the diffuse molecular ISM. Structures with spin temperature T s > 40 K, mostly with N(HCO+) ≳ 1012 cm−2, are consistent with high density, FUV radiation field, and CRIR models, characteristic of environments close to massive star formation. The latter are also found in directions with a significant fraction of thermally unstable H i. In at least one case, we rule out the PDR model parameters, suggesting that alternative mechanisms (e.g., nonequilibrium processes like turbulent dissipation and/or shocks) are required to explain the observed HCO+ in this direction. Similarly, while our observations and simulations of the turbulent, multiphase ISM agree that HCO+ formation occurs along sight lines with N(H I) ≳ 1021 cm−2, the simulated data fail to explain HCO+ column densities ≳ few × 1012 cm−2. Because a majority of our sight lines with HCO+ had such high column densities, this likely indicates that nonequilibrium chemistry is important for these lines of sight.

Atomic hydrogen (Hi) is a critical stepping stone in the gas evolution cycle of the interstellar medium (ISM) of the Milky Way. Hi traces both the cold, premolecular state before star formation and the warm, diffuse ISM before and after star formation. This review describes new, sensitive Hi absorption and emission surveys, which, together with high angular and spectral resolution Hi emission data, have revealed the physical properties of Hi, its structure, and its association with magnetic fields. We give an overview of the Hi phases and discuss how Hi properties depend on the environment and what its structure can tell us about feedback in the ISM. Key findings include the following: ▪ The mass fraction of the cold neutral medium is [Formula: see text]40% on average, increasing with AV due to the increase of mean gas density. ▪ The cold disk extends to at least R ∼ 25 kpc. ▪ Approximately 40% of the Hi is warm, with structural characteristics that derive from feedback events. ▪ Cold Hi is highly filamentary, whereas warm Hi is more smoothly distributed. We summarize future observational and simulation opportunities that can be used to unravel the 3D structure of the atomic ISM and the effects of heating and cooling on Hi properties. Expected final online publication date for the Annual Review of Astronomy and Astrophysics, Volume 61 is August 2023. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.

Interstellar shocks, a key element of stellar feedback processes, shape the structure of the interstellar medium (ISM) and are essential for the chemistry, thermodynamics, and kinematics of interstellar gas. Powerful, high-velocity shocks are driven by stellar winds, young supernova explosions, more evolved supernova remnants, cloud–cloud collisions, and protostellar outflows, whereas the existence and origin of much-lower-velocity shocks (≲10 km s−1) are not understood. Direct observational evidence for interstellar shocks in diffuse and translucent ISM environments has been especially lacking. We present the most sensitive survey to date of SiO—often considered an unambiguous tracer of interstellar shocks—in absorption, obtained with the Northern Extended Millimeter Array interferometer. We detect SiO in five of eight directions probing diffuse and translucent environments without ongoing star formation. Our results demonstrate that SiO formation in the diffuse ISM (i.e., in the absence of significant star formation and stellar feedback) is more widespread and effective than previously reported. The observed SiO line widths are all ≲4 km s−1, excluding high-velocity shocks as a formation mechanism. Yet, the SiO abundances we detect are mostly 1–2 orders of magnitude higher than those typically assumed in quiescent environments and are often accompanied by other molecular transitions whose column densities cannot be explained with UV-dominated chemical models. Our results challenge the traditional view of SiO production via stellar feedback sources and emphasize the need for observational constraints on the distribution of Si in the gas phase and grain mantles, which are crucial for understanding the physics of grain processing and the diffuse interstellar chemistry.

We have studied the small scale distribution of atomic hydrogen (H I) using 21-cm absorption spectra against multiple-component background sources from the 21-SPONGE survey and the Millennium Arecibo Absorption Line Survey. We have found > 5σ optical depth variations at a level of ∼ 0.03-0.5 between 13 out of 14 adjacent sightlines separated by a few arcseconds to a few arcminutes, suggesting the presence of neutral structures on AU scales (we refer to all AU-scale structure as tiny scale atomic structure, TSAS). The optical depth variations are strongest in directions where the H I column density and the fraction of H I in the cold neutral medium (CNM) are highest, which tend to be at low Galactic latitudes. By measuring changes in the properties of Gaussian components fitted to the absorption spectra, we find that changes in both the peak optical depth and the linewidth of TSAS absorption features contribute to the observed optical depth variations, while changes in the central velocity do not appear to strongly impact the observed variations. Both thermal and turbulent motions contribute appreciably to the linewidths, but the turbulence does not appear strong enough to confine overpressured TSAS. In a majority of cases, the TSAS column densities are sufficiently high that these structures can radiatively cool fast enough to maintain thermal equilibrium with their surroundings, even if they are overpressured. We also find that a majority of TSAS is associated with the CNM. For TSAS in the direction of the Taurus molecular cloud and the local Leo cold cloud, we estimate densities over an order of magnitude higher than typical CNM densities.