In the recent years, radiation-induced highly crosslinked polyethylenes have been introduced in arthroplasties as an alternative to conventional ultra high molecular weight polyethylene (UHMWPE) for their superior wear resistance. In the present study, the influence of the molecular weight of the raw on end-user properties of highly crosslinked polyethylenes (HXLPE) is investigated by means of a comparative study between two resins with distinct molecular weights. The main outcomes indicate that the differences in mechanical and wear properties between the row materials disappear after crosslinking; nevertheless the resin with the highest molecular weight is likely to retain a better resistance to short-term oxidation.
<p>The European standard EN 1337 on bridge bearings is supported by experimental studies dating to the ‘70s and the ‘80s, which are not suitable to account for recent issues relevant to operations of steel–PTFE bridge bearings under extreme conditions, like high environment temperatures or high velocities of sliding. The investigations reported in the paper show that the strength of PTFE at high temperatures is underestimated by the standard, leading to unnecessary need for over sizing the bearings. On the other hand, increase in wear rate and reduced service life shall be carefully considered for PTFE bearings operating at high velocities. Under severe conditions in terms of high speeds and increase in temperature at the sliding interface the actual wear life of PTFE can be dramatically reduced with respect to the figure given in the standard.</p>
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