Rarely, a close correlation between wildfires and the occurrence of channelized debris flows has been observed in the Western Italian Alps. Only two cases in history have been reported, after brief and localized rainfall events of moderate intensity in Italy's Piemonte region (NW Italy) caused debris flows, on 18 July 2005, in Verbania province (Pallanzeno municipality), and on June 2018 in Turin province (Bussoleno municipality). These phenomena occurred after a large portion of the catchments were affected by wide wildfires in the preceding months. Debris flow deposits showed an unusually large number of fine-grained particles, forming dark-brown mud-rich deposits associated with burnt wood deposits. Rainfall analysis related to the period between the wildfires' occurrence and the debris flow events, using both raingauge and weather radar data, pointed out that the debris flows triggered in July 2005 and June 2018 were characterized by greater magnitude but associated with less precipitation intensity rates as compared with previous mud flows occurring just after wildfires. These behaviors can be explained by the presence of burned organic material and fine-grained sediment, generated from the soil's thermal reworking, which formed a thick layer, centimeters deep, covering a large percentage of catchments and slopes. Most of this layer, generated by wildfires’ action were winnowed by rainfall events that had occurred in the months before the debris flow events, of significant magnitude, exhuming a discontinuous hydrophobic soil surface that changed the slopes’ permeability characteristics. In such conditions, runoff increased, corrivation time shortened, and, consequently, discharge along the two catchments’ channels-network increased as well. Consequently, the rainfall effects associated with rainfall events in July 2005 and June 2019 were more effective in mobilizing coarse sediments in channel beds than was typical for those catchments.