ResumenLa adsorción es un método ampliamente utilizado para el tratamiento de contaminantes disueltos. Diversos residuos agroindustriales han sido explorados como potenciales adsorbentes, mostrando alta eficiencia en la eliminación de colorantes. Para el escalado de este proceso se requieren modelos cinéticos y de equilibrio para cada pareja adsorbato-adsorbente. En este trabajo se evaluaron el equilibrio, la cinética y la termodinámica del sistema tuza de maíz-rojo 40 bajo sistema discontinuo a pH = 2.0 a las temperaturas de 25, 40 y 55 °C. Los modelos de Langmuir, Freundlich y Temkin fueron seleccionados para la representación de las isotermas, en tanto que las ecuaciones de Lagergren, Ho y Elovich, para la cinética del proceso. El modelo de Freundlich presentó el mejor ajuste a las isotermas, la cinética de adsorción fue mejor descrita por la ecuación de Ho y los valores para la energía libre de Gibbs, y la entropía señalaron la espontaneidad y factibilidad del proceso.Palabras clave: isotermas de adsorción, cinética, rojo 40, adsorbentes de bajo costo, tuza de maíz.
Adsorption is a widely used method for the treatment of dissolved contaminants. Various agro-industrial wastes have been explored as potential adsorbents, showing high efficiency in dye removal. Each adsorbate-adsorbent pair needs kinetic, and equilibrium models to scale up this process. In this work, the equilibrium, kinetics and thermodynamics of the corn Tuza-Red 40 system were evaluated under batch system at ph = 2.0 at temperatures of 25, 40, and 55 °C. The Langmuir, Freundlich and Temkin models were selected for the isotherm representation, while the Lagergren, Ho, and Elovich equations for the kinetics of the process. The Freundlich model presented the best fit to the isotherms, the adsorption kinetics was best described by the Ho equation, and the values for Gibbs free energy and entropy indicated the spontaneity and feasibility of the process.
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