Intelligent responsive materials have become one of the most exciting fields in the research of new materials in the past few decades due to their practical and potential applications in aerospace, biomedicine, textile, electronics, and other relative fields. Here, a novel thermal-responsive biomimetic shape memory wood composite is fabricated utilizing polycaprolactone-based (PCL) shape-memory polymer to modify treated-wood. The shape memory wood inherits visual characteristics and the unique three-dimension structure of natural wood that endows the shape memory wood (SMW) with outstanding tensile strength (10.68 MPa) at room temperature. In terms of shape memory performance, the shape recovery ratio is affected by multiple factors including environment temperature, first figuration angle, cycle times, and shows different variation tendency, respectively. Compared with shape recovery ratio, the shape fixity ratio (96%) is relatively high and stable. This study supplies more possibilities for the functional applications of wood, such as biomimetic architecture, self-healing wood veneering, and intelligent furniture.
Magnesium-cemented poplar particleboard (MCPB) is a new environmental inorganic magnesium cementitious composite without formaldehyde release. In this study, soybean flour (SM), silane coupling agent (KH560), soybean protein isolate (SPI), polyethylene glycol (PEG-400), maleic anhydride (MAH), and polyacrylic acid (PAA) were added to MCPB to improve the mechanical properties, waterproofing properties, and flame retardancy. The results show that the SPI group had the best mechanical performance; the modulus of elasticity (MOE) was up to 5192 MPa and exceeded the Chinese national standard GBT 4897-2015 (GBT) by 67.4%, the modulus of rupture (MOR) reached 17.72 MPa and exceeded GBT by 18%. Thickness swelling (TS) after 24-hour immersion was 0.29% and reached the standard of GBT (≤16%). The fire resistance test of MCPB indicated that the KH560 group improved the flame retardancy, the heat release rate (HRR) was 18kW/m2, the total smoke produced (TSP) was 0.192 m2, the total heat release (THR) was 29.71 MJ/kg, which reached the Chinese national standard GBT 8624-2012.
Magnesium-cemented straw composites (MCSC), as an environmentally friendly and energy-conserving material, have an enormous potential to achieve favorable properties, especially for bending strength. In this study, rice straw powder, fly ash, and magnesia cement (MC) were mixed to prepare MCSC. An optimization formula for composites was found to promote the bending strength by 490% from 0.28 MPa (empty sample) to 13.89 MPa (composites). From the variance results, the molar ratio of MgO/MgCl2 (M value) and addition of rice straw (As) noticeably impacted the compressive and bending strengths. The optimum schemes were:10% (weight ratio) for rice straw, 10% for fly ash (Af), 5 for M value, 12 to 15 for H value (the molar ratio of H2O/MgCl2), 20-mesh of straw powder (Ms), and 28 days for the curing time (T). Considering the different use of MCSC, if the weight vector was 0.7 (compressive strength) and 0.3 (bending strength), the optimized formula was M5H25Ms20T15daysAs10%Af10%. If the weight vector was 0.3 (compressive strength) and 0.7 (bending strength), the optimized formula was M5H10Ms20T3daysAs10%Af10%.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.