The highly efficient selective hydrogenation of 5-hydroxymethylfurfural (HMF) to 2,5-bis(hydroxymethyl)furan (BHMF) was achieved in a fixed-bed reactor by using inexpensive potassium-doped Cu/Al2O3 catalysts.
Understanding the role of pore structure and acidity of zeolite catalyst in the self-etherification of 5-hydroxymethylfurfural to 5,5′(oxy-bis(methylene))bis-2-furfural.
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