The results of studies on polymer electrolytes for metal-ion batteries are analyzed and generalized. Progress in this field of research is driven by the need for solid-state batteries characterized by safety and stable operation. At present, a number of polymer electrolytes with a conductivity of at least 10−4 S cm−1 at 25 °C were synthesized. Main types of polymer electrolytes are described, viz., polymer/salt electrolytes, composite polymer electrolytes containing inorganic particles and anion acceptors, and polymer electrolytes based on cation-exchange membranes. Ion transport mechanisms and various methods for increasing the ionic conductivity in these systems are discussed. Prospects of application of polymer electrolytes in lithium- and sodium-ion batteries are outlined. The bibliography includes 349 references.

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