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The rainwater chemistry within the Metropolitan Area of Monterrey (MAM) was studied during a one-year period (January 2019–January 2020) in seven sampling sites. The metal concentration of Zn, Fe, Cd, Cu, Ni, and Mn was analyzed in bulk samples and the toxicity potential (TP) was calculated for each metal. A canonical correspondence analysis (CCA) was applied to identify the relationship between environmental variables and metals concentrations. An average of 26.6 ± 10 mm of rainfall was obtained. A mean pH of 7.2 ± 0.3 and a mean electrical conductivity of 177.8 ± 8.7 µS cm−1 were observed. The average concentration of metals in all sites follows a descending order of Fe> Zn > Mn > Cu > Ni > Cd. The university site shows the highest averages of Fe, Zn, Cu, and Mn, which is attributed to its proximity to the metallurgical industry. The TP value of Cd reflects a risk in all sites and Fe only for the Universidad, Obispado, Pastora, and Santa Catarina sites, using as a reference value the Environmental Protection Agency (EPA) Drinking Water Regulations and Mexican norm NOM-127-SSA1-1994. The CCA analysis showed that only Ni and Cd had a strong correlation with the environmental variable of relative humidity of air.

Bulk deposition was studied along an urbanization gradient in the state of Nuevo Leon, Mexico. During a yearlong period seven sites within the Metropolitan Area of Monterrey (MAM) and two rural sites (Allende and Linares) were monitored, with the purpose of characterizing deposition and identifying possible patterns between sites. A total of 32 rainfall events were collected. An average pH of 7.15 ± 0.02 was found, which indicates the presence of neutralizing substances in rainwater, as well as an average Electrical Conductivity of 153.96 ± 6.83 μS/cm. The annual accumulated deposition follows the descending order Ca> K> Mg> Zn> Fe> Mn> Cu> Cd> Ni and does not show significant differences between urban and rural areas, with the exception of Ca (p = 0.017). The Principal Component Analysis shows that metals (Cu, Zn, Ni, Mn, and Cd) represent an important pathway in the deposition phenomena and this behavior is maintained through the urbanization gradient, which denotes that the rural areas could be connected to the air basin of the MAM. Seasonal deposition showed that Zn, Fe, Cd, Cu, Ni, Mn Ca, and Mg are higher during autumn and K during winter. Enrichment Factors shows that Zn and Cd were highly enriched, Cu and Ni were moderately enriched, and Ca, K, and Mn were not enriched. Finally, backward trajectories for rural sites showed that only for Allende site a possible carry-over of pollutants is observed during the summer, since the wind currents come preferably from the northern part of the MAM.