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Polycyclic aromatic hydrocarbons (PAHs) associated with the inhalable fraction of particulate matter were determined for 1 year (2009-2010) at a school site located in proximity of industrial and heavy traffic roads in Delhi, India. PM10 (aerodynamic diameter ≤10 μm) levels were ∼11.6 times the World Health Organization standard. Vehicular (59.5%) and coal combustion (40.5%) sources accounted for the high levels of PAHs (range 38.1-217.3 ng m(-3)) with four- and five-ring PAHs having ∼80 % contribution. Total PAHs were dominated by carcinogenic species (∼75%) and B[a]P equivalent concentrations indicated highest exposure risks during winter. Extremely high daily inhalation exposure of PAHs was observed during winter (439.43 ng day(-1)) followed by monsoon (232.59 ng day(-1)) and summer (171.08 ng day(-1)). Daily inhalation exposure of PAHs to school children during a day exhibited the trend school hours > commuting to school > resting period in all the seasons. Vehicular source contributions to daily PAH levels were significantly correlated (r = 0.94, p < 0.001) with the daily inhalation exposure level of school children. A conservative estimate of ∼11 excess cancer cases in children during childhood due to inhalation exposure of PAHs has been made for Delhi.

The study investigated the levels of organochlorine pesticides (OCPs) in different types of vegetables grown in periurban area of National Capital Region (NCR), India. Vegetable sampling was carried out in winter and summer season of 2012. A total of 20 different OCPs were determined using gas chromatography (GC) assembled with electron capture detector (ECD). Obtained results showed that average levels of ∑(20)OCP ranged from 83.8 ± 25.5 ng g(-1) in smooth gourd to 222.4 ± 90.0 ng g(-1) in cauliflower. The mean concentrations of different OCPs were observed in order of ∑HCH > ∑CHLs > drins > ∑endosulfan > ∑DDT in all vegetables except in brinjal and smooth gourd. Most of the OCP residues recorded in vegetable samples exceeded the maximum residue levels (MRLs) set by international and national regulatory agencies. Health risk assessment suggests that daily dietary OCP exposure via vegetable consumption was higher for children (mean value 4.25E-05) than adults (mean value 2.19E-05). The hazard quotient (HQ) and lifetime cancer risk (LCR) estimated from dietary exposure of these vegetables were above the acceptable limit and can be considered as a serious concern for Delhi population.

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