The compounds in stored woody biomass degrade as a result of chemical and/or biological processes during storage. These processes produce gaseous emissions. Recent studies concerning gaseous emissions from wood pellet storages are reviewed herein. The applicability of the results from pellet research to wood chips is discussed. Thorough scientific understanding on the storage phenomena of wood chips is extremely important as the threat of climate change and the need to reduce greenhouse gas emissions have led to an increased need to large scale wood chip storage to ensure supply. Typically the gases produced from stored woody biomasses are carbon monoxide (CO), carbon dioxide (CO 2), methane (CH 4), and other volatile hydrocarbons e.g. aldehydes and terpenes. CO 2 and CH 4 are greenhouse gases with high global warming potential. Chemical degradation via auto-oxidation of fats and fatty-acids seems to be the dominant mechanism for off-gassing from stored wood pellets, whereas biological processes are mainly responsible for the gaseous emission from wood chips. In confined storage spaces gaseous emissions may lead to oxygen depletion. Oxygen depletion together with a high CO concentration poses a serious health risk for those working in such conditions. The degradation processes also result in dry matter losses and in spontaneous heating and in the worst case, especially in large piles, spontaneous ignition of the stored material. Thorough and systematic scientific studies on degradation processes and their effects are needed in order to understand and minimise risks from large scale wood chips storage to human health, environment and property.

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Sludge from municipal wastewater treatment plants and organic fines from mechanical sorting of municipal solid waste (MSW) are two common widespread waste streams that are becoming increasingly difficult to utilise. Changing perceptions of risk in food production has limited the appeal of sludge use on agricultural land, and outlets via landfilling are diminishing rapidly. These factors have led to interest in thermal conversion technologies whose aim is to recover energy and nutrients from waste while reducing health and environmental risks associated with material re-use. Pyrolysis yields three output products: solid char, liquid oils and gas. Their relative distribution depends on process parameters which can be somewhat optimised depending on the end use of product. The potential of pyrolysis for the conversion of wastewater sludge (SS) and organic fines of MSW (OF) to a combustion gas and a carbon-rich char has been investigated. Pyrolysis of SS and OF was done using a laboratory fixed-bed reactor. Herein, the physical characterisation of the reactor is described, and results on pyrolysis yields are presented. Feedstock and chars have been characterised using standard laboratory methods, and the composition of pyrolysis gases was analysed using micro gas chromatography. Product distribution (char/liquid/gas) from the pyrolysis of sewage sludge and composted MSW fines at 700°C for 10 min were 45/26/29 and 53/14/33%, respectively. The combustible fractions of pyrolysis gases range from 36 to 54% for SS feedstock and 62 to 72% from OF. The corresponding lower heating value range of sampled gases were 11.8-19.1 and 18.2-21.0 MJ m, respectively.

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