SYNOPSISThe microbond technique is a modification of the single-fiber pullout test for measuring interfacial shear strength. Briefly, a cured microdroplet of material is debonded in shear from a single fiber. Ultra-high modulus polyethylene (Spectra) fibers and aramid fibers (Kevlar) were treated using a radio frequency plasma in order to increase the interfacial bond between the fibers and an epoxy resin. The treated fiber surface was subsequently analyzed by X-ray photoelectron spectroscopy (XPS) . Plasma treatment resulted in an increased concentration of oxygen containing functionalities on the fiber surface. The interfacial shear strength as determined by the microbond test increased by 118% for the Spectra fibers and by 45% for the Kevlar fibers with the same epoxy resin. Scanning electron microscopy indicated little change of the surface topography of either fiber following plasma treatment. Effects of friction and surface composition of the plasma-treated fibers is discussed. 0 1993 John Wiley & Sons, Inc.
Microbonding has been applied to measure the interfacial shear strength, r , between single carbon fiber and microdroplets of epoxy resins. The effect of thermoset cure and resin modification on this initial parameter for composite performance have been studied. The interfacial shear strength for the host fiber/epoxy system (T-300/Epon 828) increased 3 fold from a B-stage to a fully cured material. The addition of a toughening agent called "Fortifier P" to the host resin system increased T by 40%. Residual thermal stresses were calculated and their contribution to mechanical adhesion were related to friction components,
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