%'e report here a measurement of the lifetime of the first vibration state of LiF. The experiment w'as carried out using an electric-resonance molecular-beam technique and yielded the result~&0--14.3'2 & msec. This value is smaller than the prediction of Rittner's model and also smaller than estimates using existing spectroscopic data.
We have measured the spontaneous vibrational decay rates in the KF electronic ground state for v=2 → 1 and v=1 → 0 transitions in both the J=1 and the J=2 rotational states using a velocity selected molecular-beam technique. The four decay rates are self-consistent and reduce to a 1 → 0 decay rate of 2.6±0.4 s−1, which agrees with rates inferred from spectroscopic data.
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