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The title compound, C4H6O2S4, was prepared by repeating, with subtle improvements, a multi-step route originally described by Mott & Barany [J. Chem. Soc. Perkin Trans. 1 (1984) ▶, pp. 2615–2621]. The title compound was obtained for the first time as a crystalline material. The two [(methyl­sulfan­yl)carbon­yl]sulfenyl moieties are essentially perpendic­ular to each other, each approximately planar (r.m.s. deviations of 0.02 and 0.01 Å) and with a C—S—S—C torsion angle = 90.99 (6)°, which compares well with the theoretical value of 90°.