Thermal conductivity measurements were made on polyethylene samples which had been crystallized at different tem eratures in order to vary density and lamellar crystal oriented by mechanical shearing and by crystallization in a temperature gradient. The thermal conductivity increased linearly by 50% as the density went from 0.96 to 0.99 gm/cc. By orientation the conductivity was increased ten fold in the direction of molecular orientation and decreased two fold in the perpendicular direction. For samples oriented by deformation at different temperatures, the conductivity apparently correlates with birefringence. thic E ness. Tests were also made on polyethylenes which were
Highlights Inter-laboratory study with 174 participants using STRmix™ CE analysis settings resulted in larger differences in LR than PG software Differences in log(LR) due to MCMC variation were less than one order of magnitude Abstract (max 400 words)An intra and inter-laboratory study using the probabilistic genotyping (PG) software STRmix™ is reported. Two complex mixtures from the PROVEDIt set, analysed on an Applied Biosystems™ 3500 Series Genetic Analyzer, were selected. 174 participants responded.LRs were assigned, the point estimates ranging from 2 × 10 4 to 8 × 10 6 . For Sample 2 (in the order of 2000 rfu for major contributors), LRs ranged from 2 × 10 28 to 2 × 10 29 . Where LRs were calculated, the differences between participants can be attributed to (from largest to smallest impact): varying number of contributors (NoC), the exclusion of some loci within the interpretation, differences in local CE data analysis methods leading to variation in the peaks present and their heights in the input files used, and run-to-run variation due to the random sampling inherent to all MCMC-based methods.This study demonstrates a high level of repeatability and reproducibility among the participants. For those results that differed from the mode, the differences in LR were almost always minor or conservative.
SJ'nopsiSThe thermal conductivities of linear high polymers were studied experimentally and theoret.ically. A theory of thermal conductivity in linear amorphous high polymers waa derived based on a simple model of molecular structure. Predictions on the effects of molecular weight and molecular orientation on thermal conductivity taken from the theory agree with available experimental data. New data on the thermal conductivity of linear polyethylene and some polyethylene-wax blends are presented. Temperature dependence of the thermal conductivity in polyethylene was analyzed by the per cent crystallinity concept to obtain results which are in accord with the phonon theory of thermal conductivity in dielectric crystals.
The anisotropy of heat conductivity that develops on uniaxial stretching of amorp~ous high polymers has been examined theoretically and experimentally. Experimental measurements on OJ:lented. po!ystyre~es and polymethylmethacrylates show a linear increase in conductivity (paral!el to ~tre~chi?-g) With IncreasIng elongation. The slope of the relationship is sensitive to the molecular welgh~ dlstn?utlOn of the poly~er and the stretching conditions (temperature). The observations are discussed In relation to current theones of heat conduction in polymers.[This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to ] IP:
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