In this paper we consider a physical model in which a buffer receives messages from a finite number of statistically independent and identical information sources that asynchronously alternate between exponentially distributed periods in the ‘on’ and ‘off’ states. While on, a source transmits at a uniform rate. The buffer depletes through an output channel with a given maximum rate of transmission. This model is useful for a data‐handling switch in a computer network. The equilibrium buffer distribution is described by a set of differential equations, which are analyzed herein. The mathematical results render trivial the computation of the distribution and its moments and thus also the waiting time moments. The main result explicitly gives all the system's eigenvalues. While the insertion of boundary conditions requires the solution of a matrix equation, even this step is eliminated since the matrix inverse is given in closed form. Finally, the simple expression given here for the asymptotic behavior of buffer content is insightful, for purposes of design, and numerically useful. Numerical results for a broad range of system parameters are presented graphically.

We present an empirical flexible and polarizable water model which gives an improved description of the position, momentum, and dynamical (spectroscopic) distributions of H nuclei in water. We use path integral molecular dynamics techniques in order to obtain momentum and position distributions and an approximate solution to the Schrodinger equation to obtain the infrared (IR) spectrum. We show that when the calculated distributions are compared to experiment the existing empirical models tend to overestimate the stiffness of the H nuclei involved in H bonds. Also, these models vastly underestimate the enormous increase in the integrated IR intensity observed in the bulk over the gas-phase value. We demonstrate that the over-rigidity of the OH stretch and the underestimation of intensity are connected to the failure of existing models to reproduce the correct monomer polarizability surface. A new model, TTM4-F, is parametrized against electronic structure results in order to better reproduce the polarizability surface. It is found that TTM4-F gives a superior description of the observed spectroscopy, showing both the correct redshift and a much improved intensity. TTM4-F also has a somewhat improved dielectric constant and OH distribution function. It also gives an improved match to the experimental momentum distribution, although some discrepancies remain.

ABSTRACT. We present a new free resolution for k as an G-module, where G is an associative augmented algebra over a field k. The resolution reflects the combinatorial properties of G.

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