The main and new surface modification methods of activated carbon (AC) and their influence on application (adsorption capacity) were reviewed. Adsorption capacity is an important issue, contributing to hazardous substances environment management. According to literature, it is true that surface chemistry strongly affects adsorption capacity. Surface chemistry can be modified by several methods that lead to different activated carbon properties. Furthermore, adsorbate properties, and their relationships with surface structure, can impact adsorption properties. Surface modifications can be conducted by adding some atoms to the surface structure, making the surface more acidic or basic. Introduction of oxygen and ammonia atoms (chemical modification) are the main processes to make the surface more acidic and basic, respectively, although may bring chemical wastes to environment. Surface modification is done by chemical and physical modifications that lead activated carbons to present different properties. The main and new methods of chemical and physical modifications are compared and presented in this paper. Some new physical methods, like corona treatment, plasma discharge and microwave radiation, can be applied to cause surface modifications. Corona treatment can be a practical and new way to cause surface modification on an activated carbon surface.

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This study aimed to reduce the concentration of chromated copper arsenate type-C (CCA-C) in preservative treatments of Eucalyptus sp. for use in applications with ground contact. The genetic materials used were Eucalyptus cloeziana of seminal origin and the clonal hybrid (E. urophylla x E. camaldulensis), which was derived from six year old crops at commercial plantations. The basic density, moisture content, percentage of sapwood, and wood treatable volume were determined, and the anatomical structures were characterized. The genetic materials were treated with concentrations of 1.2%, 1.3%, 1.4%, 1.5%, and 1.6% active ingredients (AI) of CCA-C. The quality of the preservative treatment was evaluated via penetration and retention tests. The treated wood volume of E. cloeziana exhibited 44% irregular partial penetration, 40% vascular penetration, 12% peripheral partial penetration, and 4% no penetration. For the hybrid, the wood volume exhibited 68% total penetration, 24% peripheral partial penetration, and 8% irregular partial penetration. The concentrations of 1.4% AI and 1.5% AI for E. cloeziana and of 1.4% AI and 1.6% AI for hybrid reached the minimum retention required by standard.