David R. Slim scite author profile

The reactions of S3N3C13 with SbCIS and the reactions of S3N3F3 with AsF,, SbFS, and SO3 have been studied. The reaction of S3N3C13 with SbC1, in a 1:2 mole ratio gave (S4N4)(SbC16)2 as the major product in SO2, CH2C12, and S0C12 as solvents.With a 1:l mole ratio and CH2C12 as solvent the products were (SSNS)(SbCl6) and S4N4.SbCIs. This mixture reacted with additional SbCIS to give (S4N4)(SbC16)2. Both (SSNS)(SbCl6) and S4N4.SbCIs were characterized by X-ray crystallography. The geometry of the planar pentathiazyl cation SSN5+ is intermediate between the "azulene-like" and heart-shaped conformations found previously for other examples of this cation. This is attributed to disorder in part of the cation. The reactions of S3N3F3 with AsFS, SbF,, and SO3 in the mole ratios 1:6, 1:6, and 1:3 gave the thiazyl salts SN(AsF,), SN(Sb2F1,), and SN(S03F), respectively.

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David R. Slim

Preparation, spectroscopic properties, and crystal structures of Te6(AsF6)4.2AsF3 and Te6(AsF6)4.2SO2: a new trigonal-prismatic cluster cation, hexatellurium(4+)

Crystal structure, Raman spectrum, and nuclear magnetic resonance spectrum of methoxythionyl .mu.-fluoro-bis(pentafluoroantimonate(V)), CH3OSO+Sb2F11-

Fluoride crystal structures. Part 30. 2,2′-Bipyridylfluorodioxovanadium(V)

Preparation and crystal structures of tritellurium trisulfur bis(hexafluoroarsenate), ditellurium tetraselenium bis(hexafluoroantimonate), and ditellurium tetraselenium bis(hexafluoroarsenate)

Reactions of trifluorocyclotrithiazene (S3N3F3) and trichlorocyclotrithiazene (S3N3Cl3) with Lewis acids. Preparation and crystal structure of pentathiazyl hexachloroantimonate (S5N5)(SbCl6)

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