He/SF 6 dual-gas tracer injections were conducted during the Southern Ocean Gas Exchange Experiment (SO GasEx) to determine gas transfer velocities. During the experiment, wind speeds of up to 16.4 m s −1 were encountered. A total of 360 3 He and 598 SF 6 samples were collected at 40 conductivity-temperature-depth (CTD) rosette casts and two pumped stations. The gas transfer velocity k was calculated from the decrease in the observed 3 He/SF 6 ratio using three different approaches. Discrete points of wind speed and corresponding k were obtained from the change in 3 He/SF 6 ratio over three time intervals. The results were also evaluated using an analytical model and a 1-D numerical model. The results from the three approaches agreed within the error of the estimates of about ±13%-15% for Patch 1 and ±4% for Patch 2. Moreover, 3 He/SF 6 dual-tracer results from SO GasEx are similar to those from other areas in both the coastal and open ocean and are in agreement with existing parameterizations between wind speed and gas exchange. This suggests that wind forcing is the major driver of gas exchange for slightly soluble gases in the ocean and that other known impacts are either intrinsically related to wind or have a small effect (<20% on average) on time scales of the order of days to weeks. The functionality of the wind speed dependence (quadratic or cubic) cannot be unequivocally determined from SO GasEx results.
[1] An important aspect of particle trajectory modeling in the ocean is the assessment of the uncertainty in the final particle position. Monte Carlo particle trajectory simulations using surface currents derived from standard-range and long-range CODAR HF radar systems were performed using random-walk and random-flight models of the unresolved velocities. Velocity statistics for these models were derived from the covariance functions of differences between CODAR and drifter estimates of surface currents. Comparison of predicted trajectories and drifter tracks demonstrate that these predictions are superior to assuming the drifters stay at their initial position. Vertical shear between the effective depth of long-range CODAR measurements ($2.4 m) and that of drifters (0.65 m) causes the drifters to move more rapidly downwind than predicted. This bias is absent when standard-range CODAR currents (effective depth $0.5 m) are used, implying that drifter leeway is not the cause of the bias. Particle trajectories were computed using CODAR data and the random-flight model for 24-hour intervals using a Monte Carlo approach to determine the 95% confidence interval of position predictions. Between 80% and 90% of real drifters were located within the predicted confidence interval, in reasonable agreement with the expected 95% success rate. In contrast, predictions using the random-walk approach proved inconsistent with observations unless the diffusion coefficient was increased to approximately the random-flight value. The consistency of the random-flight uncertainty estimates and drifter data supports the use of our methodology for estimating model parameters from drifter-CODAR velocity differences.
[1] The Southern Ocean Gas Exchange Experiment (SO GasEx) is the third in a series of U.S.-led open ocean process studies aimed at improving the quantification of gas transfer velocities and air-sea CO 2 fluxes. Two deliberate 3 He/SF 6 tracer releases into relatively stable water masses selected for large DpCO 2 took place in the southwest Atlantic sector of the Southern Ocean in austral fall of 2008. The tracer patches were sampled in a Lagrangian manner, using observations from discrete CTD/Rosette casts, continuous surface ocean and atmospheric monitoring, and autonomous drifting instruments to study the evolution of chemical and biological properties over the course of the experiment. CO 2 and DMS fluxes were directly measured in the marine air boundary layer with micrometeorological techniques, and physical, chemical, and biological processes controlling air-sea fluxes were quantified with measurements in the upper ocean and marine air. Average wind speeds of 9 m s −1 to a maximum of 16 m s −1 were encountered during the tracer patch observations, providing additional data to constrain wind speed/gas exchange parameterizations. In this paper, we set the stage for the experiment by detailing the hydrographic observations during the site surveys and tracer patch occupations that form the underpinning of observations presented in the SO GasEx special section. Particular consideration is given to the mixed layer depth as this is a critical variable for estimates of fluxes and biogeochemical transformations based on mixed layer budgets.
[1] Surface current (HF radar) and velocity profile observations, obtained as part of the Front-Resolving Observational Network with Telemetry (FRONT) project over an approximately 2-year period, are used to describe the seasonal variability of a coastal jet in the Long Island Sound outflow region. The jet is observed in an area of the continental shelf where surface thermal fronts are frequently detected during both summer and winter. The current jet is coincident with a band of high summer frontal probability, and apparently arises from the interaction between Long Island Sound outflow and larger-scale alongshore currents on the shelf. The jet reaches peak strength in summer (transport of $0.07 Sv) and is weak or non-existent in winter. Flow is strongest near the surface and weakens with depth, with only moderate seasonal variations in the vertical shear. The relatively long data set of currents combined with historical hydrographic measurements and buoy wind observations is analyzed to examine the seasonal variability of the terms in the depth-averaged momentum balance. The depth-averaged pressure gradient is partitioned into a steric component, evaluated from the hydrography, and a non-steric component that is estimated as the residual of the computed terms in the momentum equation. The depth-averaged momentum balance is found to be approximately geostrophic in the across-shore direction. The seasonal variability in the jet arises due to the shifting balance between buoyancy-driven flow that is always downshelf but intensifies somewhat in summer and wind-driven flow which dominates in winter when wind stress becomes strongly upwelling favorable.
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