The yielding process of statically cooled waxy crude oil was
examined in detail. Three direct
measurementsa controlled stress test, a creep−recovery test, and
an oscillatory testwere
employed using a controlled stress rheometer to investigate the
yielding of two distinctly different
statically cooled waxy crude oils. The results showed that
yielding of waxy crude oil occurs by
an initial elastic response, followed by viscoelastic creep and a final
fracture. A model with an
elastic-limit yield stress, a static yield stress, and a dynamic yield
stress was introduced to
describe the yielding process. The three yield stresses were
determined by means of different
techniques. The effect of the time scale in different measurements
on the three yield stresses
was studied. It was shown from both the creep−recovery and
oscillatory tests that the elastic-limit yield stress was independent of the time scale. The static
yield stress was found to be
dependent on the time scale in the three tests. The dynamic yield
stress measured only with
the controlled stress test was also found to be dependent on the time
scale of the yielding. Good
reproducibility can be obtained in these tests by strictly controlling
the thermal and shear history
of the samples.
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