The partial substitution of non-renewable materials in cementitious composites with eco-friendly materials is promising not only in terms of cost reduction, but also in improving the composites’ shielding properties. The water and carbon content of a commercial lignin-based biochar is analyzed with thermal gravimetric analysis. Cementitious composite samples of lignin-based biochar with 14 wt.% and 18 wt.% are realized. Good dispersion of the filler in the composites is observed by SEM analysis. The samples are fabricated in order to fit in a rectangular waveguide for measurements of the shielding effectiveness in the X-band. A shielding effectiveness of 15 dB was obtained at a frequency of 10 GHz in the case of composites with 18 wt.% biochar. Full-wave simulations are performed by fitting the measured shielding effectiveness to the simulated shielding effectiveness by varying material properties in the simulator. Analysis of the dimensional tolerances and thickness of the samples is performed with the help of full/wave simulations. Lignin-based biochar is a good candidate for partial substitution of cement in cementitious composites, as the shielding effectiveness of the composites increases substantially.
Self-healing is recognized as a promising technique for increasing the durability of concrete structures by healing cracks, thereby reducing the need for maintenance activities over the service life and decreasing the environmental impact. Various self-healing technologies have been applied to a wide range of cementitious materials, and the performance has generally been assessed under 'ideal' laboratory conditions. Performance tests under ideal conditions, tailored to the self-healing mechanism, can demonstrate the self-healing potential. However, there is an urgent need to prove the robustness and reliability of self-healing under realistic simulated conditions and in real applications before entering the market. This review focuses on the influence of cracks on degradation phenomena in reinforced concrete structures, the efficiency of different healing agents in various realistic (aggressive) scenarios, test methods for evaluating self-healing efficiency, and provides a pathway for integrating self-healing performance into a life-cycle encompassing durability-based design.
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