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The issue of material dissolution is common in aqueous batteries, leading to serious performance deterioration. However, it is difficult to be solved so far. In this study, a single component cathode solid electrolyte interface (SEI) layer (CaSO 4 •2H 2 O) is observed via in situ electrochemically charging process, as demonstrated in a Ca 2 MnO 4 cathode for an aqueous zinc-ion battery. Density functional theory calculation confirms its electronic insulation and ionic conductor properties, indicating that it is an appropriate SEI film. The material dissolution seems to be effectively suppressed by the presence of the SEI layer on the cathode side. Meanwhile, this in situ formed interface layer is advantageous for lowering impedance, ameliorating interface, and reducing activation energy. As a result, significantly superior rate performance and cycle stability are exhibited. The observation of a protective SEI layer in an aqueous system may provide an insight into the development of high stability aqueous batteries.

The evaluation of the hydraulic properties evolution of granular sandstones in relation with groundwater inrush within faults is an important issue for mining engineering applications. This paper presents the results of an experimental investigation of small particle migration from granular sandstone samples under different original porosities, particle size compositions and water flow pressures. A new rock testing system has been setup to carry out the tests. Based on the results, it is observed that the overall permeability evolution during the tests can be divided into four different phases, including i) re-arrangement of large rock fragments, ii) water inrush with substantial particle migration, iii) continued moderate particles seepage, and iv) steady state water flow. The crushing of edges and corners of large rock fragments, and the evolution of the fracture network has mainly been observed in the first two phases of the tests. The results indicate that the migration of small particles has an essential effect on permeability and porosity increase during water inrush through fractured sandstone. The samples with higher original porosity, higher percentage of fine particles in their formation and under higher water flow pressures, achieve higher permeability and porosity values when the test is complete. Furthermore, using the measured data, the performances of a number of empirical models, for permeability evolution in fractured porous media, have been studied. The prediction results indicate that not all of the fractures in a sample domain contribute in small particle migration. There are parts of the fracture network that are not effective in particle flow, a sample with less original porosity, more fine particles and under lower water pressure shows less ineffective fractures. Therefore, using the concept of the effective porosity (fracture) is sufficient enough for the flow calculation.Keywords: granular sandstone; groundwater inrush; particle migration; permeability; porosity. A C C E P T E D M A N U S C R I P T ACCEPTED MANUSCRIPT