In this work, CdS nanocrystals (NCs) doped with Mn were synthesized in a glass matrix by fusion. The as-grown Cd1−xMnxS NCs were investigated by optical absorption, atomic force microscopy, and electron paramagnetic resonance (EPR). The incorporation of Mn2+ ions in CdS NCs was confirmed by an absorption transition blueshift with increasing Mn concentration x. EPR spectra demonstrated the existence of two distinct Mn2+ ion locations: one incorporated in the core and the other near the surface of the Cd1−xMnxS NCs. The hyperfine interaction constants used to simulate the EPR spectra were A=7.6 and 8.2 mT, respectively. The synthesis of high quality Cd1−xMnxS NCs may allow the control of optical and magnetic properties.
Various ore fractions (and mixtures thereof), of which the main metallic components are iron, copper and zinc, were analysed by means of radioisotope X‐ray fluorescence spectroscopy using a Si(Li) detector. As a result existing equations which deal with interelement effects (selective attenuation and enhancement of characteristic radiation) were further developed, and a new set of general equations, which accounts for the important interelemental background contribution, has been formulated. Its validity has been experimentally tested over a wide range of concentrations which, in some cases, varied by as much as a factor of 200. Satisfactory results were obtained.
A comparative ferromagnetic resonance (FMR) study of the magnetic properties of Si(100)[FeNi∕Al∕FeMn∕Al]×10 and Si(100)[FeMn∕Al(6Å)∕FeNi(30Å)∕Al]×20 multilayers is reported. Besides the uniform mode, the parallel and perpendicular FMR spectra of both multilayers also give evidence of additional magnetic phases in the films. The perpendicular FMR spectrum of the first multilayer also shows the presence of a volume spin-wave resonance (SWR) mode, while the spectrum of the second shows the presence of a surface SWR mode. This is attributed to the structural differences between the two multilayers in terms of the thicknesses of the magnetic (FeNi) and nonmagnetic (FeMn and Al) layers.
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