Static short-term corrosion tests were performed to two kinds of borosilicate glasses in deionized water, at 70°C and 150°C, respectively. Same corrosion experiments were also carried out in other leaching agents, such as simulated under ground water of Beishan, sulfuric acid solution (pH=0.5) and potassium hydroxide solution (pH = 13). Experimental results show that both leaching agent and corrosion temperature co-dominate the corrosion process, and the temperature plays more important role. At low temperature of 70°C, the corrosion reaction is controlled by the ion diffusing in DIW at earlier stage. While in PHS, network hydrolysis reaction is the main corrosion mechanism.

In this paper, super fine LiMn2O4 powder was synthesized by mechanochemical method starting from Li2CO3 and Mn2O3. The structure, size and morphology of LiMn2O4 were explored with X-ray diffraction and scanning electron microscopy (SEM). The electrochemical properties of LiMn2O4 were studied in 2 mol/L (NH4)2SO4 solution. The result showed that pure spinel LiMn204 powder was prepared after 8h grinding with 3.0KW of power and the particle size was about 1µm. Cyclic vohammetry curve indicate LiMn2O4 electrode material has better capacitive performances.

MCC-1 static short-term corrosion tests were performed to pyrochlore simulated waste forms in deionized water, at 90°C. Experimental results show that pyrochlore simulated waste forms has a good anti-leaching property. Both the normalized mass loss rate and the normalized mass loss of element Ce decrease with soaking time increasing in the short test. The corrosion process is co-dominated by the leaching agent and the corrosion temperature.

Yb:YAG laser ceramic nanopowders were synthesized by the carbonate altogether precipitation method, and the thermal properties with structure and morphology characterized and analyzed by the measurements of TG-DTA, XRD, IRS, SEM. The results show that well-crystallized Yb:YAG nanopowders calcined at 900°C are obtained with higher sintering performance and purity, and the average diameter is in the range of 100 nm. The crystalline size grew with the increase of the heat treatment temperature. The size of powder calcined at 1100°C is about 70-150 nm with higher purity, regular shape and even particle size distribution, which is favorable for good sinterability of Yb:YAG ceramics.Key words: Yb; YAG laser ceramic powders; nanopowders synthesis; carbonate altogether precipitation method;

3Y-TZP powder has been successfully synthesized by gel solid-state method. The structural phases of powder particles were analyzed by X-ray diffraction and the morphology was analyzed by scanning electron microscopy. The average size of grains was 230 nm. The sintering behavior, mechanical properties and microstructure of 3Y-TZP ceramics sintered by this powder were investigated. The experiment results showed that the mechanical properties of ceramics were excellent.