The present paper deals with the microstructural parameters calculated from X-ray diffraction data, electrical and optical investigations, and scanning tunneling microscopy (STM) studies on ZnIn 2 S 4 IIIa layer type CdIn 2 S 4-x Se x (1.75 e x e 2.75) quaternary chalcogenides. Microstructural parameters such as dislocation density, root-mean-square strain, stacking fault probability, crystallite size anisotropy, and layer disorder parameters of these compounds have been calculated. The temperature variation of electrical conductivity (25-400 °C) confirmed semiconducting behavior. The band gaps of all these compounds obtained from STM and optical measurements are in the range 1.57-1.77 eV and are comparable to each other irrespective of the technique used.
The present paper deals with the preparation of ZnIn2S4−IIIa layer-type CdIn2S4
-
x
Se
x
(1.75≤ x ≤ 2.75) quaternary chalcogenides and their characterization. X-ray diffraction
studies of CdIn2S4
-
x
Se
x
(1.75 ≤ x ≤ 2.75) confirmed that all of these compounds possess the
ZnIn2S4−IIIa type of structure. The variation of the composition x shows that both lattice
parameters a- and c increase with a growing amount of selenium in the crystals. The
calculation of microstructural parameters by an X-ray line profile analysis has shown that
the intercalation of lithium in the host CdIn2S2Se2 is accompanied by a decrease in crystallite
size while the dislocation density and the rms strain are increasing. The process of
intercalation results in no expansion along the c-axis, probably due to no increase in the
c-parameter at all in a given intercalation process; which does not have purely geometric
origin but also comes from electronic effects. A radial distribution function (RDF) analysis
of these quaternary chalcogenides indicated the presence of peaks at ∼2.5 and 4.5 Å metal−chalcogen and metal−metal distances, respectively. The peaks above 6 Å are due to the
higher order metal−chalcogen and chalcogen−chalcogen distances. The apparent crystallite
size of CdIn2S4
-
x
Se
x
(1.75 ≤ x ≤ 2.75) compounds deduced from X-ray studies has been
correlated with the scanning electron micrographs. Scanning tunneling microscopic studies
revealed that the surface of the CdIn2S2Se2 crystals is not smooth. All of the compounds are
thermally stable up to about 450 °C in air atmosphere.
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