Biomaterials are effective alternatives for tissue substitution, including the bone tissue, since they do not pose risks of transmission of diseases or immune rejection. Nowadays, there is an interest in new materials capable of being associated with other substances which favor bone formation, especially natural biopolymers, in particular chitosan, which may present a potential for repairing bone defects and forms films that adhere to metal surfaces. Titanium, despite being a material greatly employed in implants because of its excellent physical properties, does not present bioactive characteristics, making it necessary to use methods of surface modification to enhance its biological response, favoring bone formation. This work aims at studying commercially pure titanium (cp-Ti) coating with chitosan using the biomimetic method and the evaluation of the effects of process variables as substrate surface conditions. Subsequently, the incorporation of AgNO3 was studied and its effects on corrosion resistance were evaluated. To evaluate the coating process, several tests were conducted, such as scanning electron microscopy, X-ray diffraction and infrared spectroscopy. From the results obtained, the efficacy of the chitosan film in inhibiting the corrosion of the metals is concluded, which was the target of this study, thus justifying its use for osseointegration and in several implants.
Commercially pure titanium and its alloys have been widely applied as implant materials with excellent long-term results and present benefits compared to other metal biomaterials because of the good mechanical strength and modulus of elasticity with values close to those of the bone. Titanium implants coated with hydroxyapatite give the metal a bioactive surface, which induces a direct connection between the implant and the bone tissue. As a consequence, the time for osseointegration, and hence the total treatment time, may be reduced. This paper aimed at studying the bactericidal effect of silver nitrate at 10 ppm and 100 ppm, incorporated in the layer on the surface of commercial titanium. The results showed efficiency in both osseointegration and bactericidal effect, confirmed by scanning electron microscopy, X-ray diffraction and corrosion tests. The bacterial culture tests, by means of the halo inhibition tests, indicate that the doping with AgNO3in concentrations 10 and 100 ppm did not present significant variation.
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