No abstract

No abstract

Designing durable, highly active supported Pt catalysts has attracted tremendous interest in recent years due to their high electrocatalytic activities and stability in methanol oxidation reactions (MORs). Herein, we report an eco-friendly synthetic strategy for obtaining Pt/CeO 2 composite microspheres, which are highly active and durable catalysts for MOR. The porous CeO 2 microspheres were prepared through a hydrothermal method using the Piper longum fruit extract, which is an environmentally friendly solvent. The Pt nanoparticles (NPs) with an average size of ∼5 nm dispersed on CeO 2 microspheres were obtained by the chemical reduction of Pt 2+ ions at room temperature. It was found that the supported Pt NPs are strongly coupled through strong metal−support interactions (SMSIs), which promoted the formation of oxygen vacancies (OVs) and increased the concentration of active Ce 3+ sites. Owing to the presence of high OVs and of Ce 3+ species, the Pt/CeO 2 microsphere catalyst revealed enhanced MOR performance, with specific activity (SA) as high as 36.37 mA/cm 2 and mass activity (MA) of 229.44 mA/mg, which are substantially higher than those of commercial catalysts such as Pt/C and Pt/CeO 2 prepared with commercial CeO 2 nanoparticles. Moreover, the resultant catalyst showed excellent durability, retaining about 76.2% of its initial current density even after 5000 potential cycles. The used green extractmediated synthesis process can be a promising alternative to conventional methods for the rational design of highly active metal nanoparticle-supported catalysts for heterogeneous catalysts.

No abstract