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A green and facile protocol of thermal treatment of graphene oxide (GO) with urea was adopted to synthesize nitrogen-doped graphene (NG-Urea-air) at a low temperature (350 °C) in the static air. The resulting sample exhibited outstanding catalytic performance to activate peroxymonosulfate (PMS) toward organic degradation. The NG-Urea-air induced 49.7- and 11.5-fold enhancement over GO and pristine reduced graphene oxide (rGO-air). Moreover, the influences of nitrogen precursors including organic chemicals (urea, cyanamide, and melamine) and inorganic salts (ammonium nitrate and ammonium chloride) were investigated, and urea was demonstrated to be the best precursor for synthesizing N-doped graphene with a relative high doping level (18.7 at.%). The classical radical quenching and advanced in situ electron paramagnetic resonance (EPR) technology revealed that the outstanding oxidative effectiveness of PMS/NG-Urea-air system was originated from the nonradical oxidation pathway, in which PMS was activated by the positively charged carbon domains next to nitrogen atoms and the phenol was oxidized simultaneously on the carbon network via rapid charge transfer. Meanwhile, singlet oxygen and radicals may also partially contribute to the complete phenol degradation. This study facilitates a fundamental investigation of heteroatom doping progress during thermal treatment and sheds light on the insights into carbocatalysis in environmental remediation

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Cubic Pt nanoparticles were prepared by NaBH4 reduction of K2PtCl6 in an aqueous medium. Under the effect of phase-transfer inducer HCl, Pt nanoparticles were transferred to a toluene solution containing dodecanethiol, forming a toluene organosol of cubic Pt nanoparticles protected by dodecanethiol. A monolayer of cubic Pt nanoparticles is obtained on carbon film by self-assembly using this organosol. The stability of the organosol is checked; after being aged for 10 months, the same monolayer of cubic Pt nanoparticles can be obtained using the organosol. The organosol, Pt nanoparticle self-assembled monolayer, and phase transfer were characterized by UV−vis spectra and transmission electron microscopy.