This study presents a geochemical framework and geographic information system (GIS) method for assessing the intrinsic potential of surface water and groundwater to mobilize arsenic, molybdenum, selenium, uranium, and vanadium. The method was created using published groundwater and surface water geochemical data from the National Uranium Resource Evaluation database for 2302 groundwater and 915 surface water samples. The method was evaluated using published groundwater geochemical data from the Texas Water Development Board. Geochemical data were analyzed in GIS. Samples were categorized by environmental condition, which was determined by using reduction–oxidation—as indicated by pe—and pH ranges for each sample based on geochemical mobility frameworks developed by Smith (2007) and Perel’man (1986). Reduction–oxidation and pH influence the occurrence, persistence, and mobility of arsenic, molybdenum, selenium, uranium, and vanadium in groundwater and surface water. Reduction–oxidation categories were assigned to water samples using concentrations of redox-active constituents, including dissolved oxygen, iron, manganese, and sulfur. The presence of iron substrates and hydrogen sulfides were considered in relation to mobility mechanisms. Twelve-digit hydrologic unit code (HUC) boundaries were used in GIS as analysis areas to determine the most commonly occurring environmental condition in each HUC. The resulting maps identify the environmental conditions in different areas that can be used to identify where the elements are mobile. This methodology provides a systematic approach to identify areas where elements in groundwater and surface water may occur and persist and may be transferable to other locations.

The Rio Grande/Río Bravo del Norte (hereinafter referred to as the “Rio Grande”) is the primary source of recharge to the Mesilla Basin/Conejos-Médanos aquifer system in the Mesilla Valley of New Mexico and Texas. The Mesilla Basin aquifer system is the U.S. part of the Mesilla Basin/Conejos-Médanos aquifer system and is the primary source of water supply to several communities along the United States–Mexico border in and near the Mesilla Valley. Identifying the gaining and losing reaches of the Rio Grande in the Mesilla Valley is therefore critical for managing the quality and quantity of surface and groundwater resources available to stakeholders in the Mesilla Valley and downstream. A gradient self-potential (SP) logging survey was completed in the Rio Grande across the Mesilla Valley between 26 June and 2 July 2020, to identify reaches where surface-water gains and losses were occurring by interpreting an estimate of the streaming-potential component of the electrostatic field in the river, measured during bankfull flow. The survey, completed as part of the Transboundary Aquifer Assessment Program, began at Leasburg Dam in New Mexico near the northern terminus of the Mesilla Valley and ended ~72 kilometers (km) downstream at Canutillo, Texas. Electric potential data indicated a net losing condition for ~32 km between the Leasburg Dam and Mesilla Diversion Dam in New Mexico, with one ~200-m long reach showing an isolated saline-groundwater gaining condition. Downstream from the Mesilla Diversion Dam, electric-potential data indicated a neutral-to-mild gaining condition for 12 km that transitioned to a mild-to-moderate gaining condition between 12 and ~22 km downstream from the dam, before transitioning back to a losing condition along the remaining 18 km of the survey reach. The interpreted gaining and losing reaches are substantiated by potentiometric surface mapping completed in hydrostratigraphic units of the Mesilla Basin aquifer system between 2010 and 2011, and corroborated by surface-water temperature and conductivity logging and relative median streamflow gains and losses, quantified from streamflow measurements made annually at 16 seepage-measurement stations along the survey reach between 1988 and 1998 and between 2004 and 2013. The gaining and losing reaches of the Rio Grande in the Mesilla Valley, interpreted from electric potential data, compare well with relative median streamflow gains and losses along the 72-km long survey reach.

A previously completed mineral resources assessment of the Texas Coastal Plain indicated the potential for the future discovery of uranium resources. Geoenvironmental assessments that include the hydrogeologic framework can be used as a tool to understand the potential effects of mining operations. The hydrogeologic framework for this study focused on the composite hydrogeologic unit of the tract permissive for the occurrence of uranium consisting of the upper part of the Miocene-age Fleming Formation/Lagarto Clay, Pliocene-age Goliad and Pleistocene-age Willis Sands, Pleistocene-age Lissie and Beaumont Formations, and Holocene-age alluvial sediments (fluvial alluvium and eolian sand deposits). This composite hydrogeologic unit, which contains the Chicot and Evangeline aquifers of the Gulf Coast aquifer system, is intended for inclusion in a regional-scale geoenvironmental assessment of as yet undiscovered uranium resources. This article provides (1) a brief literature review describing the geologic and hydrogeologic settings, (2) the methodology used to develop a composite hydrogeologic framework, and (3) descriptions and maps of the land-surface altitude, composite hydrogeologic unit base and midpoint depth, water-level altitude, depth of water, unsaturated and saturated zone thickness, and transmissivity and hydraulic conductivity. A composite hydrogeologic unit, created by combining geologic and hydrogeologic data and maps for individual geologic and hydrogeologic units, is intended for use as a tool in a geoenvironmental assessment to evaluate potential contaminant migration through various avenues. Potential applications include using the hydrogeologic framework as an input into a geoenvironmental assessment to help estimate the potential for (1) runoff of contaminants into surface water, (2) infiltration of contaminants into the groundwater (aquifers), or (3) movement of contaminants from the mining area through wind, groundwater-flow, or streamflow in a given permissive tract. The procedures outlined in this paper also provide a method for developing hydrogeologic frameworks that can be applied in other areas where mining may occur.

A geoenvironmental assessment methodology was developed to estimate waste quantities and disturbances that could be associated with the extraction of undiscovered uranium resources and identify areas on the landscape where uranium and other constituents of potential concern (COPCs) that may co-occur with uranium deposits in this region are likely to persist, if introduced into the environment. Prior to this work, a method was lacking to quantitively assess the environmental aspects associated with potential development of undiscovered uranium resources at a scale of a uranium resource assessment. The mining method of in situ recovery (ISR) was historically used to extract uranium from deposits in the Goliad Sand of the Texas Coastal Plain. For this reason, the study’s methodology projected the following types of wastes and disturbances commonly associated with ISR based on historical ISR mining records: the mine area, affected aquifer volume, mine pore volume, water pumped and disposed during uranium extraction and restoration, and radon emissions. Within the tract permissive for the occurrence of undiscovered uranium resources, maps and statistics of factors were derived that indicate the potential contaminant pathways. The percentage of days meeting the criteria for air stagnation indicate the potential for radon accumulation; the geochemical mobility of COPCs in groundwater in combination with effective recharge indicates the potential for infiltration of surface-derived COPCs; the geochemical mobility of COPCs in groundwater combined with hydraulic conductivity indicates the propensity for transmitting fluids away from contaminated or mined aquifers; and finally, geochemical mobility of COPCs in surface water combined with the factor for climatic erosivity (R factor) indicates the potential for COPCs to persist in surface waters due to runoff. This work resulted in a new methodology that can be applied to any undiscovered mineral resource to better understand possible wastes and disturbances associated with extraction and identify areas on the landscape where COPCs are likely to persist.

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