Organic remains preserved on eight copper alloy artifacts of the Byzantine Collection of the Benaki Museum with an Egyptian provenance were investigated, implementing a multi-analytical approach combining microscopy-FTIR and GC/MS. The transmission spectra of powder samples provided important information on the vessels regarding inorganic and organic components. In the latter case, subsequent extractions with a range of solvents allowed discrimination of components with different polarities and provided data on the suitability of the solvents for the acquisition of more informative spectra. GC/MS was implemented for the detailed characterization of the compounds present in the samples because of the complex nature of the residues preserved. A wide range of fatty acid oxidation products was identified, including a series of α, ω-dicarboxylic acids typical of such remains. In addition, vicinal dihydroxy-docosanoic and dihydroxy-eicosanoic acid, oxidation products of erucic and gondoic acid, respectively, were detected. Both are found in abundance in oils from plants belonging to the Brassicaceae family and imply their multiple uses in medieval Egypt.
Twelve 'Japanned' metal trays from Greece and Turkey, dated in the 19 th century, were subjected to macroscopic and microscopic examination (stereoscopy, metallography, scanning electron microscopy) as well as to XRF and SEM-EDX analysis. The trays represent two stylistic types made of wrought iron either tin-plated or protected with a primer. Two were manufactured by forging while the rest were made by rolling prior to die forming with drop hammers or machine presses. Wrought iron was produced indirectly from cast iron with fossil fuels. Only in one case charcοal fuel was implied. Most pure iron was recognized for four trays dated at the end of the 19 th century. Three of them also revealed the deliberate incorporation of metallic manganese while one of them was found to be alloyed. The other metals used such as copper, brass, silver and tin as also the methods applied, seem to follow the industrial evolution of the iron substrate but more analysis is required. As regards origin, the metallurgical results, even limited, combined with historical information, indicated that the metals/techniques used, were probably originally produced in west Europe although the supply of materials could have depended on different sources.
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