Electroreduction of carbon dioxide (CO(2))--a key component of artificial photosynthesis--has largely been stymied by the impractically high overpotentials necessary to drive the process. We report an electrocatalytic system that reduces CO(2) to carbon monoxide (CO) at overpotentials below 0.2 volt. The system relies on an ionic liquid electrolyte to lower the energy of the (CO(2))(-) intermediate, most likely by complexation, and thereby lower the initial reduction barrier. The silver cathode then catalyzes formation of the final products. Formation of gaseous CO is first observed at an applied voltage of 1.5 volts, just slightly above the minimum (i.e., equilibrium) voltage of 1.33 volts. The system continued producing CO for at least 7 hours at Faradaic efficiencies greater than 96%.

This Perspective highlights recent efforts and opportunities in the heterogeneous electrochemical conversion of carbon dioxide to help address the global issues of climate change and sustainable energy production. Recent research has shown that the electrochemical reduction of CO 2 can produce a variety of organic compounds such as formic acid, carbon monoxide, methane, and ethylene with high current efficiency. These products can be used as feedstocks for chemical synthesis or converted into hydrocarbon fuels. This process is of interest (i) for the recycling of CO 2 as an energy carrier, thereby reducing its accumulation in the atmosphere, (ii) for the production of renewable hydrocarbon fuels from CO 2 , water, and renewable electricity for use as transportation fuels, and (iii) as a convenient means of storing electrical energy in chemical form to level the electrical output from intermittent energy sources such as wind and solar. Accomplishments to date in this field of study have been encouraging, yet substantial advances in catalyst, electrolyte, and reactor design are needed for CO 2 utilization via electrochemical conversion to become a technology that can help address climate change and shift society to renewable energy sources.

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