In this work, the capture of carbon dioxide using a dense hollow fiber membrane was studied experimentally and theoretically. The factors affecting the flux and recovery of carbon dioxide were studied using a lab-scale system. Experiments were conducted using a mixture of methane and carbon dioxide to simulate natural gas. The effect of changing the CO2 concentration from 2 to 10 mol%, the feed pressure from 2.5 to 7.5 bar, and the feed temperature from 20 to 40 °C, was investigated. Depending on the solution diffusion mechanism, coupled with the Dual sorption model, a comprehensive model was implemented to predict the CO2 flux through the membrane, based on resistance in the series model. Subsequently, a 2D axisymmetric model of a multilayer HFM was proposed to simulate the axial and radial diffusion of carbon dioxide in a membrane. In the three domains of fiber, the CFD technique was used to solve the equations for the transfer of momentum and mass transfer by using the COMSOL 5.6. Modeling results were validated with 27 experiments, and there was a good agreement between the simulation results and the experimental data. The experimental results show the effect of operational factors, such as the fact that temperature was directly on both gas diffusivity and mass transfer coefficient. Meanwhile, the effect of pressure was exactly the opposite, and the concentration of CO2 had almost no effect on both the diffusivity and the mass transfer coefficient. In addition, the CO2 recovery changed from 9% at a pressure equal to 2.5 bar, temperature equal to 20 °C, and a concentration of CO2 equal to 2 mol%, to 30.3% at a pressure equal to 7.5 bar, temperature equal to 30 °C, and concentration of CO2 equal 10 mol%; these conditions are the optimal operating point. The results also manifested that the operational factors that directly affect the flux are pressure and CO2 concentration, while there was no clear effect of temperature. This modeling offers valuable data about the feasibility studies and economic evaluation of a gas separation unit operation as a helpful unit in the industry.

Heavy oil and bitumen are making up approximately 70 percent of the remaining estimated hydrocarbon reserves. Many Enhanced Oil Recovery (EOR) methods such as chemical flooding, thermal recovery, gas injection, etc., were developed to make advances in the production of unconventional oil. Among all the variety of EOR methods, thermal recovery produces practically all of the heavy oil and bitumen among the various EOR methods. But at the same time, throughout its application, there are several disadvantages were revealed such as it is an expensive and not environmentally friendly process, heat loss in surface facilities and distribution lines, the efficiency is low after injection, increases in the extracted oil’s surface viscosity have caused polymerization reactions of free radicals created during the steam injection process, and the requirement for continuous steam injection is attempting to keep a hot oil-water interface at the front of the flow. For these reasons, the solvent-based non-thermal recovery method can be used to enhance heavy oil and bitumen recovery in unconventional reservoirs (thin or deep reservoirs) to prevent or reduce unwanted effects as described above. Toluene, carbon dioxide (CO2), ethane, propane, normal butane, and mixture solvents, among others, can be used as the injection solvent for the solvent-based non-thermal recovery method. That is why the researchers have concentrated on carbon dioxide as a solvent with Huff & Puff method to develop the production of heavy oil and bitumen to overcome all these negative issues because CO2 has several characteristics that make it an excellent option for this application. In this paper, the CO2 Huff and Puff method is reviewed. The CO2 Huff and Puff method’s viscosity reduction and oil swelling procedures have been the most significant factors in increasing heavy oil production. As a results, impacts of oil swelling at various temperatures and pressures as well as the viscosity reduction ratio with CO2 injection have been studied.

Petroleum is a mixture of many different hydrocarbon compounds, most of which primarily contain carbon and hydrogen in varying proportions. Monocyclic aromatic hydrocarbons, which are small, explosive, and volatile, to large, non-volatile, are all included in the mixture of hydrocarbons. Toxicological effects of a hydrocarbon depend on its molecular weight, family of hydrocarbons, creature exposed to it, and life-cycle stage of the exposed organism. Studies have shown that exposure to the toxic chemicals in crude oil, such as para-phenol compounds and volatile benzene, might have an adverse effect on human health. Furthermore, when there is an oil spill at sea, the wind and water currents disperse the oil, causing a thin slick to migrate across the ocean’s surface. There are numerous simultaneous chemical and physical changes. Reviewing the long-term effects of petroleum on the environment is the aim of this paper in terms of the impact on human health, plants, and marine life.

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This paper aims to demonstrate the importance of natural gas as a substantial source of energy as an alternative to crude oil, with the increase in global demand for it in the future, and the importance of this source for Iraq at the economic and environmental level. This article provides an overview of Iraq's natural gas reserves and the geographical distribution of this reserve over the regions of Iraq, in addition to the companies operating and developer there. The challenges facing the export and industry of gas in Iraq, the quantities of gas that are flared annually, and the associated financial and environmental damage were also presented. Finally, if the quantities of produced gas were to be invested, Iraq would achieve a significant improvement in the economic and environmental level.