It is a frequent practice nowadays to use mean annual conversion factors (CFs) when performing lifecycle assessment (LCA) of processes and products that use electricity supplied by the grid. In this paper, we conduct an hourly assessment of the greenhouse gas (GHG) emission factor, along with the conversion factors for the cumulative energy demand (CED) and its non-renewable part (CEDnr), of electricity supplied by the Swiss grid and its direct neighboring countries (France, Germany, and Austria; Italy being neglected). Based on an hourly inventory of energy flows during a one-year period (2015 e2016), this attributional approach allows performance of various certification procedures of process or product manufacturing, and comparison of energy and carbon intensities of different national mixes. Hourly calculation allows evaluation of the order of magnitude of errors made when considering an annual mix. Visualization techniques are used to better understand the obtained data and to detect when strategies involving timing optimization of electricity use may be efficient. A case study is chosen to illustrate the relevance of hourly CFs when performing LCA associated to the exploitation of a given building. Moreover, mean annual CFs of interest are discriminated by electricity end-use sectors. This could be of great help for system designers willing to improve the assessment accuracy when hourly CFs are not readily available.
A magnetic hyperthermia cancer treatment strategy that does not operate by means of conventional heating mechanisms is presented. The proposed approach consists of injecting a gel with homogeneously distributed magnetic nanowires into a tumor. Upon the application of a low-frequency rotating or circularly polarized magnetic field, nanowires spin around their center of viscous drag due to torque generated by shape anisotropy. As a result of external rotational forcing and fluid friction in the nanoparticle's boundary layer, heating occurs. The nanowire dynamics is theoretically and experimentally investigated, and different feasibility proofs of the principle by physical modeling, which adhere to medical guidelines, are presented. The magnetic nanorotors exhibit rotations and oscillations with quite a steady center of gravity, which proves an immobile behavior and guarantees a time-independent homogeneity of the spatial particle distribution in the tumor. Furthermore, a fluid dynamic and thermodynamic heating model is briefly introduced. This model is a generalization of Penne's model that for this method reveals theoretic heating rates that are sufficiently high, and fits well into medical limits defined by present standards.
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