The introduction of particulate and oxides of nitrogen (NOx) after-treatment controls on heavy-duty vehicles has spurred the need for fleet emissions data to monitor their reliability and effectiveness. The University of Denver has developed a new method for rapidly measuring heavy-duty vehicles for gaseous and particulate fuel specific emissions. The method was recently used to collect 3088 measurements at a Port of Los Angeles location and a weigh station on I-5 in northern California. The weigh station NOx emissions for 2014 models are 73% lower than 2010 models (3.8 vs 13.9 gNOx/kg of fuel) and look to continue to decrease with newer models. The Port site has a heavy-duty fleet that has been entirely equipped with diesel particulate filters since 2010. Total particulate mass and black carbon measurements showed that only 3% of the Port vehicles measured exceed expected emission limits with mean gPM/kg of fuel emissions of 0.031 ± 0.007 and mean gBC/kg of fuel emissions of 0.020 ± 0.003. Mean particulate emissions were higher for the older weigh station fleet but 2011 and newer trucks gPM/kg of fuel emissions were nevertheless more than a factor of 30 lower than the means for pre-DPF (2007 and older) model years.
A method for varying the supersaturation in a turbulent mixing CNC has been used to examine heterogeneous
nucleation of different compounds (working fluid) on various nuclei's compositions. Supersaturation was
controlled by changing the vapor pressure of working fluid in nozzle flow, which was accomplished by
saturating only a predetermined fraction of the flow while the keeping the total flow and temperature constant.
This approach allows the partial pressure of the working fluid to be varied while maintaining a constant flow
structure and temperature field. Experimental results characterizing the initial stages of heterogeneous nucleation
are presented for NaCl, KCl, AgCl, and Ag particles. Heterogeneous nucleation was examined at various
pressures of dibutylphthalate, octadecane, octadecanol, and octadecanoic acid. For octadecanoic acid as the
working fluid, the size distribution of the grown particles is unimodal with the size increasing with increasing
pressure of the working fluid. For the other working fluids, the initial size distribution splits into a bimodal
distribution with one mode approximately the same as the initial distribution and a larger sized mode that
grows with increasing pressure of the condensing vapor. For NaCl and octadecane and octadecanol, the initial
unimodal size distribution splits into a trimodal size distribution.
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