Activated carbons obtained from rice husk exhibit low specific surface areas when physical activation is applied due to its high silica content. The purpose of this work was to improve textural parameters of powdered activated carbons obtained from rice husk. To avoid the negative influence of the raw material ash content, a leaching step was included in the preparation process. Hydrofluoric acid, in two concentrations (25 and 50 wt %), was used as leaching agent and applied in different stages of the process. Physical activation using water vapor as activating agent was applied. Specific surface area and porosity were evaluated from nitrogen adsorption data. When a leaching step was included, specific surface area values between 700 and 1200 m2/g were obtained. These values are higher than that corresponding to the activated carbon prepared from rice husk not treated with acid (290 m2/g). Pore size distribution depends on the step sequence of the preparation process and on the HF concentration.
-The results of studies on briquetting activated-carbon-based adsorbent materials, prepared from raw materials from the region of Cuyo, Argentina, are reported in this article. Several steps were carried out to obtain activated-carbon briquettes from Eucalyptus camaldulensis Dehn wood. These steps included carbonization of wood to obtain char; blending of char and a novel binder, i.e., grape must; formation of cylinder-like briquettes by pressure; and activation of the resulting material. The material was activated with steam under different temperatures, activation times, and activating agent flow rates. Impact resistance index, axial compressive strength, tensile strength by diametrical compression, BET area, and pore volume were measured for product characterization. Satisfactory surface areas and mechanical strengths were found in the final products.
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