Chinese pine (Pinus tabuliformis Carr.) is the main forest species in northern China, with the potential to dramatically affect biotic and abiotic aspects of ecosystems in this region. To discover the rainfall partitioning patterns of different growth periods of Chinese pine forest, we studied the throughfall (Tf), stemflow (Sf) and canopy interception (I) in three stand ages (40-, 50-, 60-year-old) in Liaoheyuan Natural Reserve of Hebei Province during the growing seasons of 2013 and 2014, and analyzed effect of rainfall amount, rainfall intensity, and canopy structure on rainfall partitioning in Chinese pine forest. The results showed that throughfall decreased with the stand age, accounting for 78.8%, 74.1% and 66.7% of gross rainfall in 40-, 50- and 60-year-old Chinese pine forests, respectively. Canopy interception, on the other hand, increased with the stand age (20.4%, 24.8%, and 32.8%, respectively), while the pattern in stemflow was less clear (0.8%, 1.1%, and 0.6%, respectively). As rainfall intensity increased, the Tf and Sf increased and I declined. Additionally, our results showed that leaf area index (LAI) and the diameter at breast height (DBH) increased with age in Chinese pine stands, probably explaining the similar increase in canopy interception (I). On the other hand, the mean leaf angle, openness, gap fraction all decreased with the stand age. Stepwise regression analysis showed that the rainfall amount and LAI were the major determinants influencing the rainfall partition. Our study highlights the importance of stand age in shaping different forest canopy structures, and shows how age-related factors influence canopy rainfall partitioning. This study also significantly adds to our understanding the mechanisms of the hydrological cycle in coniferous forest ecosystems in northern China.